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Merck
CN

200050

Chromium(III) chloride

purified by sublimation, 99%

Synonym(s):

Chromic chloride, Chromium trichloride

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About This Item

Linear Formula:
CrCl3
CAS Number:
10025-73-7
Molecular Weight:
158.36
NACRES:
NA.23
PubChem Substance ID:
24851955
UNSPSC Code:
12352302
EC Number:
233-038-3
MDL number:
MFCD00010948
Assay:
99%
Form:
flakes

Key Documents

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Product Name

Chromium(III) chloride, purified by sublimation, 99%

InChI key

QSWDMMVNRMROPK-UHFFFAOYSA-K

InChI

1S/3ClH.Cr/h3*1H;/q;;;+3/p-3

SMILES string

Cl[Cr](Cl)Cl

assay

99%

form

flakes

purified by

sublimation

reaction suitability

core: chromium
reagent type: catalyst

impurities

<0.2% water

density

2.87 g/mL at 25 °C (lit.)

Quality Level

200

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Application

Chromium(III) chloride can be used in the formation of a catalytic system for the conversion of glucose into 5-hydroxymethylfurfural (HMF). It can also be used in the preparation of ionic liquid mixtures using choline chloride and water with improved ion mobility and conductivity.
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.2

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Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Met. Corr. 1 - Skin Sens. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV3099
MKCW3523
MKCW4391
MKCT0753
MKCR4439

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Physicochemical properties of ionic liquid mixtures containing choline chloride, chromium (III) chloride and water: effects of temperature and water content
Protsenko VS, et al.
Ionics, 23(3), 637-643 (2017)
Efficient conversion of glucose into 5-hydroxymethylfurfural by chromium (III) chloride in inexpensive ionic liquid
Hu L, et al.
Industrial & Engineering Chemistry Research, 51(3), 1099-1104 (2012)
M A Sipowicz et al.
Toxicology letters, 93(1), 9-14 (1998-02-12)
The tissue levels of chromium were followed after single intraperitoneal or subcutaneous injection of 1 mmol CrCl3/kg body wt. in Swiss male mice. Blood levels were similar after both treatment modes, with half-lives of 31-41 h. Organs not directly exposed
Mobilization of trivalent chromium in presence of organic acids: a hydroponic study of wheat plant (Triticum vulgare).
S Srivastava et al.
Bulletin of environmental contamination and toxicology, 63(4), 524-530 (1999-09-29)
M Pesti et al.
FEMS microbiology letters, 182(2), 375-380 (2000-01-06)
The in vivo effects of CrCl(3) on an ergosterol-producing 33 erg(+) strain of the eukaryotic yeast Candida albicans, and on its ergosterol-deficient erg(-)2 mutant, were studied by using electron paramagnetic resonance spectroscopy. A 5-doxylstearic acid spin probe was applied to
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