20026
2-tert-Butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine on polystyrene
extent of labeling: ~2.2 mmol/g base loading
Synonym(s):
BEMP on polystyrene
SMILES string
[X]N1[P](=NC(C)(C)C)(N(CCC1)C)N(CC)CC
form
solid
reaction suitability
reaction type: solution phase peptide synthesis, reactivity: proton reactive
extent of labeling
~2.2 mmol/g base loading
particle size
200-400 mesh
Quality Level
Related Categories
Other Notes
Polymer-bound BEMP
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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R. Schwesinger
Chimia, 39, 269-269 (1985)
Elena Chiurchiù et al.
Molecules (Basel, Switzerland), 24(24) (2019-12-19)
Highly functionalized furans are the key scaffolds of many pharmaceuticals and bioactive natural products. Herein, we disclose a new fruitful synthesis of polyfunctionalized furans starting from β-nitroenones and α-functionalized ketones. The protocol involves two steps promoted by solid supported species
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