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Merck
CN

20026

2-tert-Butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine on polystyrene

extent of labeling: ~2.2 mmol/g base loading

Synonym(s):

BEMP on polystyrene

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About This Item

UNSPSC Code:
12352128
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Form:
solid
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SMILES string

[X]N1[P](=NC(C)(C)C)(N(CCC1)C)N(CC)CC

form

solid

reaction suitability

reaction type: solution phase peptide synthesis, reactivity: proton reactive

extent of labeling

~2.2 mmol/g base loading

particle size

200-400 mesh

Quality Level

Other Notes

Polymer-bound BEMP

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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R. Schwesinger
Chimia, 39, 269-269 (1985)
Elena Chiurchiù et al.
Molecules (Basel, Switzerland), 24(24) (2019-12-19)
Highly functionalized furans are the key scaffolds of many pharmaceuticals and bioactive natural products. Herein, we disclose a new fruitful synthesis of polyfunctionalized furans starting from β-nitroenones and α-functionalized ketones. The protocol involves two steps promoted by solid supported species

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