20423
(tert-Butoxycarbonylmethyl)triphenylphosphonium chloride
≥98.0%
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About This Item
Linear Formula:
(CH3)3COCOCH2P+(C6H5)3Cl
CAS Number:
Molecular Weight:
412.89
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4116684
Assay:
≥98.0%
Form:
solid
InChI
1S/C24H26O2P.ClH/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-18H,19H2,1-3H3;1H/q+1;/p-1
SMILES string
[Cl-].CC(C)(C)OC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI key
PWEGQXPODNSKMU-UHFFFAOYSA-M
assay
≥98.0%
form
solid
reaction suitability
reaction type: C-C Bond Formation
Application
Reactant for:
- Stereoselective preparation of (arylamino)quinazoline derivatives bearing tethered acrylamide moieties as inhibitors of epidermal growth factor receptor and histone deacetylase
- Thermal decomposition reactions
Other Notes
Reagent for Wittig-reactions ; Synthesis of α-diazophosphonium salts
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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B.B. Snider et al.
Journal of the American Chemical Society, 101, 6023-6023 (1978)
M.P. Cooke et al.
The Journal of Organic Chemistry, 47, 4955-4955 (1982)
M. Regitz et al.
Liebigs Ann. Chem., 1865-1865 (1981)
Rhushikesh A Kulkarni et al.
Nature chemical biology, 15(4), 391-400 (2019-02-06)
Hereditary cancer disorders often provide an important window into novel mechanisms supporting tumor growth. Understanding these mechanisms thus represents a vital goal. Toward this goal, here we report a chemoproteomic map of fumarate, a covalent oncometabolite whose accumulation marks the
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