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Merck
CN

206237

Sigma-Aldrich

Iridium(IV) oxide

99.9% trace metals basis

Synonym(s):

Iridium dioxide, Iridium oxide

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About This Item

Linear Formula:
IrO2
CAS Number:
Molecular Weight:
224.22
EC Number:
MDL number:
UNSPSC Code:
12352303
eCl@ss:
38191204
PubChem Substance ID:
NACRES:
NA.23
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Quality Level

Assay

99.9% trace metals basis

form

powder

application(s)

battery manufacturing

SMILES string

O=[Ir]=O

InChI

1S/Ir.2O

InChI key

HTXDPTMKBJXEOW-UHFFFAOYSA-N

General description

Iridium oxide is a ceramic material with unique properties like long-term stability, sensitivity, electrochemical catalytic activity, and excellent biocompatibility. It can be formed from Ir metal by different methods like thermal decomposition, reactive sputtering, and electrochemical deposition. It is widely used in bio-electronic devices.

Application

Iridium(IV) oxide can be used as:
  • An indicator electrode in solid-state pH sensors.
  • Coating material for stimulation electrodes.
  • An anodic catalyst for oxygen evolution through a water-splitting reaction in a polymer electrolyte membrane (PEM) cell.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Yoon Sung Nam et al.
Nanoscale, 4(11), 3405-3409 (2012-05-11)
A highly porous electrode comprised of biologically templated iridium oxide-gold (IrO(2)-Au) hybrid nanowires is introduced for electrochromic applications. A filamentous M13 virus is genetically engineered to display IrO(2)-binding peptides on the viral surface and used as a template for the
Xin Zhou et al.
The journal of physical chemistry. A, 116(40), 9985-9995 (2012-09-19)
The geometric structures and relative stabilities of small iridium oxide nanoclusters, Ir(m)O(n) (m = 1-5 and n = 1-2m), have been systematically investigated using density functional theory (DFT) calculations at the B3LYP level. Our results show that the lowest-energy structures
Elisabet Prats-Alfonso et al.
Biosensors & bioelectronics, 39(1), 163-169 (2012-08-04)
This work demonstrates the implementation of iridium oxide films (IROF) grown on silicon-based thin-film platinum microelectrodes, their utilization as a pH sensor, and their successful formatting into a urea pH sensor. In this context, Pt electrodes were fabricated on Silicon
Chia-Ching Wang et al.
Langmuir : the ACS journal of surfaces and colloids, 27(23), 14253-14259 (2011-11-04)
In this study, we employed density functional theory (DFT) to investigate the oxidation of ammonia (NH(3)) on the IrO(2)(110) surface. We characterized the possible reaction pathways for the dehydrogenation of NH(x) species (x = 1-3) and for the formation of
Narayanappa Sivasankar et al.
Journal of the American Chemical Society, 133(33), 12976-12979 (2011-07-21)
A surface hydroperoxide intermediate has been detected upon oxidation of water at an Ir oxide nanocluster catalyst system under pulsed excitation of a [Ru(bpy)(3)](2+) visible light sensitizer by recording of the OO vibrational mode at 830 cm(-1). Rapid-scan FT-IR spectroscopy

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