206261
Rhodium(III) chloride hydrate
Rh 38-40%, powder or crystals
Synonym(s):
Rhodium trichloride hydrate
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About This Item
Linear Formula:
RhCl3 · xH2O
CAS Number:
Molecular Weight:
209.26 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
233-165-4
MDL number:
Product Name
Rhodium(III) chloride hydrate, Rh 38-40 %
form
powder or crystals
Quality Level
composition
Rh, 38-40%
reaction suitability
core: rhodium, reagent type: catalyst
mp
100 °C (dec.) (lit.)
SMILES string
O.Cl[Rh](Cl)Cl
InChI
1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3
InChI key
HSSMNYDDDSNUKH-UHFFFAOYSA-K
Application
Catalyst for the direct conversion of methane to acetic acid.
Catalyst for conjugate reduction of cinnamaldehydes followed by cross-coupling with arylboronic acids.
Catalyst for the isomerization of alkenes, the reduction of aromatic rings, the oxidation ofalkenes, the hydration of acetylene, the hydrosilylation of α,β-unsaturated esters to form dimethylketene trimethylsilyl acetals.
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Muta. 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Storage Class
11 - Combustible Solids
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Chemical Communications (Cambridge, England), 1192-1192 (2004)
Sen, A. et al.
Nature, 368, 613-613 (1994)
See Wee Chee et al.
Nature communications, 11(1), 2133-2133 (2020-05-03)
The dynamical structure of a catalyst determines the availability of active sites on its surface. However, how nanoparticle (NP) catalysts re-structure under reaction conditions and how these changes associate with catalytic activity remains poorly understood. Using operando transmission electron microscopy
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 206261-250MG | 04061838768575 |
| 206261-1G | 04061838768568 |
| 206261-10G | 04061838768551 |
| 206261-25G | 04061833397961 |
| 206261-5G | 04061835508563 |