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Merck
CN

208272

Vanadium(III) chloride

97%

Synonym(s):

Vanadium trichloride

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About This Item

Linear Formula:
VCl3
CAS Number:
Molecular Weight:
157.30
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Assay:
97%
Form:
powder
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Quality Level

Assay

97%

form

powder

reaction suitability

core: vanadium
reagent type: catalyst

density

3 g/mL at 25 °C (lit.)

SMILES string

Cl[V](Cl)Cl

InChI

1S/3ClH.V/h3*1H;/q;;;+3/p-3

InChI key

HQYCOEXWFMFWLR-UHFFFAOYSA-K

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General description

Vanadium(III) chloride is a crystalline solid with variable oxidation states. It is widely used as a catalyst in organic synthesis, polymerization processes, and redox batteries. It acts as a reducing agent.

Application

Vanadium chloride may be used as a reduction agent to determine nitrates and nitrites in water samples.It may be used in redox flow batteries. Vanadium trichloride catalyses Pinacol coupling reactions of benzaldehyde in water. it also acts as a mild and efficient catalyst for the chemoselective deprotection of acetonides.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品
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Lingjun Kong et al.
Small (Weinheim an der Bergstrasse, Germany), 14(21), e1800639-e1800639 (2018-04-20)
Hierarchical porous structures are highly desired for various applications. However, it is still challenging to obtain such materials with tunable architectures. Here, this paper reports hierarchical nanomaterials with oriented 2D pores by taking advantages of thermally instable bonds in vanadium-based
Heyam Mohamed Ali Sidahmed et al.
BMC complementary and alternative medicine, 13, 183-183 (2013-07-23)
Mitrella kentii (M. kentii) (Bl.) Miq, is a tree-climbing liana that belongs to the family Annonaceae. The plant is rich with isoquinoline alkaloids, terpenylated dihydrochalcones and benzoic acids and has been reported to possess anti-inflammatory activity. The purpose of this
A M Dolgorukova et al.
Bulletin of experimental biology and medicine, 165(5), 635-639 (2018-09-19)
The study of NO metabolism in chicken embryos showed that the intensity of oxidation of both endogenous and exogenous for the embryo NO donors to nitrate is determined by the presence or state of NO targets, rather than donor concentration.
Novel vanadium chloride/polyhalide redox flow battery.
Skyllas-Kazacos M
Journal of Power Sources, 124(1), 299-302 (2003)
Chiara Pennesi et al.
PloS one, 8(10), e76870-e76870 (2013-11-10)
The use of dried and re-hydrated biomass of the seagrass Posidonia oceanica was investigated as an alternative and -low-cost biomaterial for removal of vanadium(III) and molybdenum(V) from wastewaters. Initial characterisation of this biomaterial identified carboxylic groups on the cuticle as

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