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About This Item
Linear Formula:
VCl3
CAS Number:
Molecular Weight:
157.30
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-744-6
MDL number:
Assay:
97%
Form:
powder
InChI key
HQYCOEXWFMFWLR-UHFFFAOYSA-K
InChI
1S/3ClH.V/h3*1H;/q;;;+3/p-3
SMILES string
Cl[V](Cl)Cl
assay
97%
form
powder
reaction suitability
core: vanadium, reagent type: catalyst
density
3 g/mL at 25 °C (lit.)
Quality Level
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General description
Vanadium(III) chloride is a crystalline solid with variable oxidation states. It is widely used as a catalyst in organic synthesis, polymerization processes, and redox batteries. It acts as a reducing agent.
Application
Vanadium chloride may be used as a reduction agent to determine nitrates and nitrites in water samples.It may be used in redox flow batteries. Vanadium trichloride catalyses Pinacol coupling reactions of benzaldehyde in water. it also acts as a mild and efficient catalyst for the chemoselective deprotection of acetonides.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
supp_hazards
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
危险化学品
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Vanadium (III) chloride: A mild and efficient catalyst for the chemoselective deprotection of acetonides.
Sabitha G, et al.
J. Mol. Catal. A: Chem., 238(1), 229-232 (2005)
Chiara Pennesi et al.
PloS one, 8(10), e76870-e76870 (2013-11-10)
The use of dried and re-hydrated biomass of the seagrass Posidonia oceanica was investigated as an alternative and -low-cost biomaterial for removal of vanadium(III) and molybdenum(V) from wastewaters. Initial characterisation of this biomaterial identified carboxylic groups on the cuticle as
Xiaoliang Xu et al.
The Journal of organic chemistry, 70(21), 8594-8596 (2005-10-08)
A catalytic pinacol coupling using water as a solvent was performed by a catalytic amount of vanadium(III) chloride and metallic Al as a co-reductant. A combination forms a binary catalytic system, being in sharp contrast to the reaction in organic
Mustafa Ahmed Abdel-Reheim et al.
Pharmaceutical biology, 55(1), 1972-1983 (2017-07-22)
Saponins from different sources are historically reported in Chinese medicine to possess many beneficial effects. However, insufficient experimental data are available regarding the hepatoprotective potential of Quillaja bark saponin. The protective effect of Quillaja saponaria Molina (Quillajaceae) bark triterpenoid saponin
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Medical principles and practice : international journal of the Kuwait University, Health Science Centre, 27(2), 122-128 (2018-02-23)
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