213187
2-Methyl-5-nitroanisole
99%
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About This Item
Linear Formula:
CH3C6H3(NO2)OCH3
CAS Number:
Molecular Weight:
167.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
236-048-6
MDL number:
Assay:
99%
assay
99%
mp
69-71 °C (lit.)
SMILES string
COc1cc(ccc1C)[N+]([O-])=O
InChI
1S/C8H9NO3/c1-6-3-4-7(9(10)11)5-8(6)12-2/h3-5H,1-2H3
InChI key
WVQGZNRUEVFXKR-UHFFFAOYSA-N
Application
2-Methyl-5-nitroanisole was used in the synthesis of:
- 2-methoxy-p-toluidine via reduction with tin and hydrochloric acid
- 2-methoxy-4-nitrobenzyl bromide
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Anodic oxidations. VII. Nuclear cyanation of methylanisoles.
Yoshida K, et al.
The Journal of Organic Chemistry, 40(1), 63-66 (1975)
P K Chakraborty et al.
International journal of radiation applications and instrumentation. Part A, Applied radiation and isotopes, 42(7), 673-681 (1991-01-01)
The synthesis of 4-[18F]fluoroguaiacol (4-[18F]fluoro-2-methoxyphenol) has been achieved in no-carrier-added form starting from 2-methoxy-4-nitrobenzaldehyde, using nucleophilic aromatic substitution by [18F]fluoride followed by Baeyer-Villiger oxidation of the benzaldehyde to the phenol. Demethylation with boron tribromide gave 4-[18F]fluorocatechol (1,2-dihydroxy-4-[18F]fluorobenzene) with an overall
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 213187-10G | 04061838772619 |
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