214914
N,N-Dimethylmethyleneiminium iodide
98%
Synonym(s):
N,N-Dimethylmethyleneammonium iodide, Eschenmoser’s salt
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Linear Formula:
CH2=N+(CH3)2I-
CAS Number:
Molecular Weight:
185.01
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
251-680-2
Beilstein/REAXYS Number:
1731022
MDL number:
Assay:
98%
Quality Level
assay
98%
mp
219 °C (dec.) (lit.)
solubility
water: soluble 50 mg/mL, clear to slightly hazy, colorless to yellow
functional group
amine
SMILES string
[I-].C[N+](C)=C
InChI
1S/C3H8N.HI/c1-4(2)3;/h1H2,2-3H3;1H/q+1;/p-1
InChI key
VVDUZZGYBOWDSQ-UHFFFAOYSA-M
General description
N,N-Dimethylmethyleneiminium iodide is useful reagent for many synthetic applications, especially aminomethylation and conversion of ketones to α,β−unsaturated enones.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
A new method using 2-chloro-4, 6-dimethoxy-1, 3, 5-triazine for facile elimination of dimethylamino group in Eschenmoser's methylenation for synthesis of a, ?-unsaturated esters.
Yamada K, et al.
Tetrahedron Letters, 54(13), 1753-1760 (2013)
Tetrahedron Asymmetry, 5, 921-921 (1994)
Masayuki Inoue et al.
The Journal of organic chemistry, 72(8), 3065-3075 (2007-03-16)
(-)-Merrilactone A [(-)-1], isolated from Illicium merrillianum in 2000, possesses neurite outgrowth activity in cultures of fetal rat cortical neurons, and, therefore, is expected to show therapeutic potential for the treatment of neurodegeneration associated with Alzheimer's and Parkinson's diseases. Apart
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 214914-10G | 04061838773234 |
| 214914-50G | 04061832763217 |