217050
2-Methoxy-1,3-dioxolane
99%
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About This Item
Empirical Formula (Hill Notation):
C4H8O3
CAS Number:
Molecular Weight:
104.10
EC Number:
243-229-3
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
103177
MDL number:
Product Name
2-Methoxy-1,3-dioxolane, 99%
InChI key
VRAYTNFBRROPJU-UHFFFAOYSA-N
InChI
1S/C4H8O3/c1-5-4-6-2-3-7-4/h4H,2-3H2,1H3
SMILES string
COC1OCCO1
assay
99%
form
liquid
refractive index
n20/D 1.409 (lit.)
bp
129-130 °C (lit.)
density
1.092 g/mL at 25 °C (lit.)
functional group
ether
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Application
2-Methoxy-1,3-dioxolane was used in the synthesis of :
- [4,5-bis(hydroxymethyl)-1,3-dioxolan-2-yl]nucleosides, potential inhibitors of HIV
- diastereoisomeric cyclic acetals
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Synthesis of highly substituted 2, 6-anti-configured tetrahydropyrans. First steps towards an efficient access to amphidinol 3 ring system.
Dubost C, et al.
Tetrahedron Letters, 46(23), 4005-4009 (2005)
Jonas Brånalt et al.
The Journal of organic chemistry, 61(11), 3599-3603 (1996-05-31)
The synthesis of 1,3-dioxolan-2-ylnucleosides and related chemistry is described. We have shown that 2-methoxy-1,3-dioxolane (6) reacts with silylated thymine and trimethylsilyl triflate to give the acyclic formate ester 1-[2-(formyloxy)ethyl]thymine (8) rather than 1-(1,3-dioxolan-2-yl)thymine (7). A tentative mechanism which could explain
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