217344
Trichloroacetamide
99%
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About This Item
Linear Formula:
Cl3CCONH2
CAS Number:
Molecular Weight:
162.40
EC Number:
209-849-3
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1754028
MDL number:
InChI key
UPQQXPKAYZYUKO-UHFFFAOYSA-N
InChI
1S/C2H2Cl3NO/c3-2(4,5)1(6)7/h(H2,6,7)
SMILES string
NC(=O)C(Cl)(Cl)Cl
assay
99%
form
solid
bp
238-240 °C (lit.)
mp
139-141 °C (lit.)
General description
Trichloroacetamide is the major degradation product of trichloroacetonitrile.
Application
Trichloroacetamide was used in microarray-based transcriptomics and one-dimensional proton nuclear magnetic resonance based metabonomics to investigate the health effects of nitrogenous disinfection byproducts of trichloroacetamide in mice.
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Zheng Liu et al.
Organic letters, 12(13), 2974-2977 (2010-06-04)
Stereocontrolled syntheses of alpha-C-GalCer (2) and its alpha-C-acetylenic analogue 6 were accomplished in high efficiency by a convergent construction strategy from 1-hexadecene and d-galactose. The key transformations include Sonogashira coupling, Sharpless asymmetric epoxidation, and Et(2)AlCl-catalyzed cyclization of an epoxytrichloroacetimidate to
A E Christina et al.
Carbohydrate research, 356, 282-287 (2012-03-16)
Reported is the gram-scale synthesis of tert-butyldiphenylsilyl 4-(N-benzyloxycarbonyl)-amino-2-azido-2,4,6-trideoxy-β-D-galactopyranoside, which represents an orthogonally protected 2,4-diamino-D-fucose building block, a common constituent of various zwitterionic polysaccharides. The building block has been synthesized from D-glucosamine in 19% overall yield over 14 steps, requiring 5
Chan Lan Chun et al.
Environmental science & technology, 41(5), 1615-1621 (2007-04-03)
Disinfection byproducts (DBPs) in drinking water flowing through corroded iron or steel pipes may encounter carbonate green rust (GR(CO32-)), a mixed Fe(II)/Fe(lll) hydroxide mineral and potent reductant. This research was performed to investigate the kinetics and pathways of the degradation
Ophélie Milhomme et al.
Carbohydrate research, 356, 115-131 (2012-02-24)
The synthesis of the anthrax tetrasaccharide, amenable for conjugation, has been envisaged by both [2+2] and [1+3] approaches from D-fucose and L-rhamnose. The successful route reported herein relies on a [1+3] strategy in which the 1,2-trans-glycosidic linkages have been secured
Jeffrey S Arnold et al.
Journal of the American Chemical Society, 134(20), 8380-8383 (2012-05-09)
The rhodium-catalyzed regio- and enantioselective amination of racemic tertiary allylic trichloroacetimidates with a variety of aniline nucleophiles is a direct and efficient route to chiral α,α-disubstituted allylic N-arylamines. We describe the first dynamic kinetic asymmetric transformations of racemic tertiary allylic
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