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Merck
CN

217905

Copper(II) fluoride

98%

Synonym(s):

Cupric fluoride

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About This Item

Empirical Formula (Hill Notation):
CuF2
CAS Number:
Molecular Weight:
101.54
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-147-3
MDL number:
Assay:
98%
Form:
powder
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InChI key

GWFAVIIMQDUCRA-UHFFFAOYSA-L

InChI

1S/Cu.2FH/h;2*1H/q+2;;/p-2

SMILES string

F[Cu]F

assay

98%

form

powder

reaction suitability

core: copper

loss

<0.5% loss on drying, 105 °C, 1h

mp

950 °C (dec.) (lit.)

density

4.23 g/mL at 25 °C (lit.)

Quality Level

General description

Copper fluoride is a monoclinic weak ferromagnet. The structural properties were investigated by neutron diffraction.

Application

Copper fluoride can act as an intermediate in the green synthesis of fluoro aromatics.

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

危险化学品
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T Akimoto et al.
Shika zairyo, kikai = Journal of the Japanese Society for Dental Materials and Devices, 9(2), 320-325 (1990-03-01)
As a model experiment to understand the mechanism of adhesion of the MMA-TBBO resin to dentin, MMA-TBBO was polymerized using a decalcified dentin sheet treated with aqueous citric acid (CA) solutions of copper fluoride (CF), ferric fluoride (FF), or ferric
Daisuke Tomita et al.
Chemistry, an Asian journal, 1(1-2), 161-166 (2007-04-19)
A new method for the catalytic enantioselective alkenylation and arylation of aldehydes involves the activation of alkenyl and aryl boronates by a catalytic amount of the Cu(I)F-DTBM-segphos complex through transmetalation, generating novel alkenyl and aryl copper species. These reagents act
T Akimoto et al.
Shika zairyo, kikai = Journal of the Japanese Society for Dental Materials and Devices, 8(3), 425-430 (1989-05-01)
As a model experiment to understand the mechanism of adhesion of the MMA/TBBO resin to dentin, polymerization of MMA/TBBO was investigated in the presence of a collagen sheet treated with the aqueous citric acid (CA) solutions of copper fluoride (CF)
Magnetic and crystal structure of copper(II) fluoride
Fischer P, et al.
Journal of Physics and Chemistry of Solids, 35(12), 1683-1689 (1974)
M Maltz et al.
Scandinavian journal of dental research, 96(5), 390-392 (1988-10-01)
Topical applications of 10 mM CuF2, 10 mM CuSO4, or 20 mM NaF solutions were performed twice a day in hamsters infected with S. mutans and maintained on a high sucrose diet. Animals receiving the copper compounds exhibited lower plaque

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