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Merck
CN

219576

(1S)-(+)-10-Camphorsulfonyl chloride

97%

Synonym(s):

(+)-Camphor-10-sulfonyl chloride, (1S)-Camphor-10-sulfonic acid chloride

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About This Item

Empirical Formula (Hill Notation):
C10H15ClO3S
CAS Number:
21286-54-4
Molecular Weight:
250.74
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
24853136
EC Number:
244-314-8
Beilstein/REAXYS Number:
3205974
MDL number:
MFCD00064156

Key Documents

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Product Name

(1S)-(+)-10-Camphorsulfonyl chloride, 97%

InChI key

BGABKEVTHIJBIW-GMSGAONNSA-N

InChI

1S/C10H15ClO3S/c1-9(2)7-3-4-10(9,8(12)5-7)6-15(11,13)14/h7H,3-6H2,1-2H3/t7-,10-/m1/s1

SMILES string

[H][C@@]12CC[C@@](CS(Cl)(=O)=O)(C(=O)C1)C2(C)C

assay

97%

form

solid

mp

65-67 °C (lit.)

functional group

ketone

Quality Level

200

Related Categories

Application

Chiral resolving agent. Used in the synthesis of nonpeptide oxytocin antagonists.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN6532
BCCN5784
BCCJ0850
BCCB7158
BCCC0671

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B E Evans et al.
Journal of medicinal chemistry, 35(21), 3919-3927 (1992-10-16)
The first nonpeptide antagonists of the neurohypophyseal hormone, oxytocin (OT) are described. Derivatives of the spiroindenepiperidine ring system, these compounds include L-366,509, an orally bioavailable OT antagonist with good in vivo duration. The potential use of these agents for treatment
Synthesis, 947-947 (1992)
T Jira et al.
Die Pharmazie, 48(11), 829-833 (1993-11-01)
Investigations on direct separation by RP-HPLC of selected enantiomeric beta-adrenergic active agents are described. R- and S-1-phenylethylisocyanate (PEIC) as well as (1S)-(+)-campher-10-sulfonylchloride (CSC) are used for the derivatization of the compounds. Correlations between chromatographic data and various influences (pH, temperature

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