219584
2,6-Di-tert-butylpyridine
≥97%
Synonym(s):
2,6-Bis(1,1-dimethylethyl)pyridine, 2,6-Ditert-butylpyridine
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About This Item
Empirical Formula (Hill Notation):
C13H21N
CAS Number:
Molecular Weight:
191.31
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-557-6
Beilstein/REAXYS Number:
125886
MDL number:
Assay:
≥97%
Form:
liquid
Quality Level
assay
≥97%
form
liquid
refractive index
n20/D 1.473 (lit.)
bp
100-101 °C/23 mmHg (lit.)
density
0.852 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CC(C)(C)c1cccc(n1)C(C)(C)C
InChI
1S/C13H21N/c1-12(2,3)10-8-7-9-11(14-10)13(4,5)6/h7-9H,1-6H3
InChI key
UWKQJZCTQGMHKD-UHFFFAOYSA-N
General description
Reactivity of 2,6-di-tert-butylpyridine with iron(III) tetraphenylporphyrin pi-cation radical has been examined by proton NMR spectroscopy. Reaction of 2,6-di-tert-butylpyridine with methyl iodide and methyl fluorosulfonate under high pressure has been reported.
Application
2,6-Di-tert-butylpyridine was used as proton trapping agent to investigate the living polymerization of isobutylene. It was also used with cerric ammonium nitrate in the α-enolation of aldehydes leading to 1,4-dicarbonyl systems.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
159.8 °F - closed cup
flash_point_c
71 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Enantioselective organocatalytic singly occupied molecular orbital activation: the enantioselective alpha-enolation of aldehydes.
Hye-Young Jang et al.
Journal of the American Chemical Society, 129(22), 7004-7005 (2007-05-15)
Karolina A Tarach et al.
ChemSusChem, 12(3), 633-638 (2018-12-07)
A new theoretical and practical framework has been developed through operando study of the zeolite catalytic cracking of low-density polyethylene (as a model reaction) under reaction conditions. Results show that microporous ZSM-5 gives rise to less cracking products. Hierarchical ZSM-5
Reactions of crowded molecules under high pressure. Reactions of 2, 6-di-tert-butylpyridine with methyl iodide and methyl fluorosulfonate under high pressure.
Okamoto Y and Lee KI.
Journal of the American Chemical Society, 97(!4), 4015-4018 (1975)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 219584-25G | 04061837662966 |
| 219584-5G | 04061838776068 |
| 219584-1G | 04061838776051 |