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About This Item
Linear Formula:
LiBH4
CAS Number:
Molecular Weight:
21.78
NACRES:
NA.22
PubChem Substance ID:
EC Number:
241-021-7
MDL number:
UNSPSC Code:
12352306
Assay:
≥90%
Form:
solid
Quality Segment
assay
≥90%
form
solid
reaction suitability
reagent type: reductant
greener alternative product characteristics
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sustainability
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mp
275 °C (dec.)
density
0.666 g/mL at 25 °C (lit.)
SMILES string
[Li+].[BH4-]
InChI
1S/BH4.Li/h1H4;/q-1;+1
InChI key
UUKMSDRCXNLYOO-UHFFFAOYSA-N
General description
Lithium borohydride, a white solid, may be prepared from the exchange reaction of LiCl and sodium borohydride in isopropylamine. The orthorhombic crystal structure converts to tetragonal at 108oC and eventually melting at 278oC. Infrared and Raman spectral studies at 80oC have been reported in a study.
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Application
Versatile reducing agent for aldehydes, ketones, acid chlorides, lactones, epoxides, and esters. Applied in the lithiation of 2H-WS2 giving high yields of exfoliated WS2, and opening the way to new intercalation compounds and nanocomposites. Lithium borohydride is used as hydrogen storage system. It regenerates hydrogen at 320-380oC at 10atm (H2 pressure).
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Signal Word
Danger
Hazard Codes
Precautionary Statements
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 2
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
supp_hazards
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B - Water-react. 1
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