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224464

(1S,2R,5S)-(+)-Menthol

Name: (1S,2R,5S)-(+)-Menthol
Brand: ALDRICH

99%

Synonym(s):

(+)-Menthol, (1S,2R,5S)-2-Isopropyl-5-methylcyclohexanol

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₂₀O

CAS Number:

15356-60-2

Molecular Weight:

156.27

UNSPSC Code:

12352212

NACRES:

NA.22

PubChem Substance ID:

24853440

EC Number:

239-387-8

Beilstein/REAXYS Number:

1902292

MDL number:

MFCD00062983

Assay:

99%

Form:

solid

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Properties

vapor pressure

0.8 mmHg ( 20 °C)

Quality Level

100

assay

99%

form

solid

optical activity

[α]23/D +48°, c = 10 in ethanol

optical purity

ee: 96% (GLC)

bp

103-104 °C/9 mmHg (lit.)

mp

43-44 °C (lit.)

functional group

hydroxyl

SMILES string

CC(C)[C@H]1CC[C@H](C)C[C@@H]1O

InChI

1S/C10H20O/c1-7(2)9-5-4-8(3)6-10(9)11/h7-11H,4-6H2,1-3H3/t8-,9+,10-/m0/s1

InChI key

NOOLISFMXDJSKH-AEJSXWLSSA-N

Gene Information

human ... UGT1A4(54657)

Description

General description

(1S,2R,5S)-(+)-menthol is a chiral secondary alcohol. Its alcohol group can be protected as 2-tetrahydrofuranyl ether by reacting with bromotrichloromethane and tetrahydrofuran.

Application

(1S,2R,5S)-(+)-menthol can undergo acylation with acid anhydrides in the presence of trimethylsilyl trifluoromethanesulfonate to form the corresponding acylated products.

pictograms

GHS05,GHS07

signalword

Danger

hcodes

H315,H318,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

213.8 °F - closed cup

flash_point_c

101 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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An extremely powerful acylation reaction of alcohols with acid anhydrides catalyzed by trimethylsilyl trifluoromethanesulfonate.

Procopiou PA, et al.

The Journal of Organic Chemistry, 63(7), 2342-2347 (1998)

An efficient and extremely mild method for protecting alcohols as 2-tetrahydrofuranyl ethers.

Barks JM, et al.

Tetrahedron Letters, 41(32), 6249-6252 (2000)

Global Trade Item Number

SKU	GTIN
224464-10G	04061838779069
224464-50G	04061838779076