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Merck
CN

225460

Diironnonacarbonyl

98%, solid

Synonym(s):

Enneacarbonyldiiron, Iron enneacarbonyl, Nonacarbonyldiiron

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About This Item

Linear Formula:
Fe2(CO)9
CAS Number:
Molecular Weight:
363.78
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
239-359-5
MDL number:
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Product Name

Diironnonacarbonyl, 98%

InChI key

JCXLZXJCZPKTBW-UHFFFAOYSA-N

InChI

1S/9CO.2Fe/c9*1-2;;

SMILES string

[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O=C1[Fe]2C(=O)[Fe]1C2=O

assay

98%

form

solid

reaction suitability

core: iron
reagent type: catalyst

storage temp.

2-8°C

Quality Level

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Application

Reacts with phenylsilanes to give triply bridged diiron complexes.

pictograms

FlameSkull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Sol. 2 - Water-react 2

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Kerber, R. C. et al.R. C.; Ribakove, E. C.
Organometallic News, 10, 2848-2848 (1991)
Gree, R.
Synthesis, 341-341 (1989)
Simons, R.S. Tessier, C.A.
Organometallics, 15, 2604-2604 (1996)
Crump, S. L.; Netka, J.; Rickborn, B.
The Journal of Organic Chemistry, 50, 2746-2746 (1985)
Robert Ponec et al.
Journal of computational chemistry, 29(9), 1387-1398 (2008-01-16)
The nature of the bonding in the above carbonyls was studied using the analysis of domain averaged Fermi holes (DAFH). The results straightforwardly confirm the conclusions of earlier theoretical studies in which the existence of direct metal-metal bond, anticipated for

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