226076
Benzaldehyde dimethyl acetal
99%
Synonym(s):
α,α-Dimethoxytoluene
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About This Item
Linear Formula:
C6H5CH(OCH3)2
CAS Number:
Molecular Weight:
152.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-413-0
Beilstein/REAXYS Number:
2044501
MDL number:
Assay:
99%
Form:
liquid
Quality Level
assay
99%
form
liquid
refractive index
n20/D 1.493 (lit.)
bp
87-89 °C/18 mmHg (lit.)
density
1.014 g/mL at 25 °C (lit.)
functional group
acetal, ether, phenyl
SMILES string
COC(OC)c1ccccc1
InChI
1S/C9H12O2/c1-10-9(11-2)8-6-4-3-5-7-8/h3-7,9H,1-2H3
InChI key
HEVMDQBCAHEHDY-UHFFFAOYSA-N
General description
The abstraction of α-hydrogen atoms from benzaldehyde dimethyl acetal by active bromine at 80°C has been investigated.
Benzaldehyde dimethyl acetal is derived from the condensation reaction between benzaldehyde and methanol. It is used as a protecting group.
Benzaldehyde dimethyl acetal is derived from the condensation reaction between benzaldehyde and methanol. It is used as a protecting group.
Application
Benzaldehyde dimethyl acetal used as an effective reagent for the construction of selenocarbonyl compounds.
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
156.2 °F - closed cup
flash_point_c
69 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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One-pot synthesis of orthogonally protected sugars through sequential base-promoted/acid-catalyzed steps: A solvent-free approach with self-generation of a catalytic species
Traboni S, et al.
Tetrahedron Letters, 60, 1777-1780 (2019)
1151. Polar influences in radical reactions. Part IV. The abstraction of benzylic hydrogen atoms from substituted benzyl methyl ethers and benzaldehyde dimethyl acetals by atomic bromine.
Huang RL and Lee KH.
Journal of the Chemical Society, 5963-5969 (1964)
Tetrahedron Letters, 33, 7865-7865 (1992)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 226076-100G | 04061838779977 |
| 226076-500G | 04061838779984 |