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Merck
CN

226157

N-Boc-hydroxylamine

≥98%

Synonym(s):

tert-Butyl N-hydroxycarbamate

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About This Item

Linear Formula:
(CH3)3COCONHOH
CAS Number:
Molecular Weight:
133.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
252-836-2
Beilstein/REAXYS Number:
1756546
MDL number:
Assay:
≥98%
Form:
solid
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Product Name

N-Boc-hydroxylamine, ≥98%

InChI key

DRDVJQOGFWAVLH-UHFFFAOYSA-N

InChI

1S/C5H11NO3/c1-5(2,3)9-4(7)6-8/h8H,1-3H3,(H,6,7)

SMILES string

CC(C)(C)OC(=O)NO

assay

≥98%

form

solid

mp

53-55 °C (lit.)

functional group

amine

storage temp.

2-8°C

Quality Level

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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Brian S Bodnar et al.
The Journal of organic chemistry, 72(10), 3929-3932 (2007-04-14)
The addition of azides to acylnitroso hetero-Diels-Alder cycloadducts derived from cyclopentadiene affords exo-triazolines in excellent yield. The reaction is greatly affected by the level of alkene strain, while sterically demanding azides do not hinder the reaction. Conversion of the triazolines
Synthetic Communications, 22, 2579-2579 (1992)
Tetrahedron Letters, 33, 5055-5055 (1992)
Useful hydroxylamine derivatives for the synthesis of hydroxamic acids.
Tetrahedron Letters, 33(35), 5055-5058 (1992)
M J Lee et al.
Journal of medicinal chemistry, 35(20), 3648-3652 (1992-10-02)
In the preceding paper, analogs of chlorpropamide with an OMe substituent on the sulfonamide nitrogen were shown to inhibit aldehyde dehydrogenase (AlDH), and it was postulated that these compounds were bioactivated by O-demethylation to release nitroxyl (HN = O, nitrosyl

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