Skip to Content
Merck
CN

226173

(1S)-(−)-Camphanic chloride

98%

Synonym(s):

(−)-Camphanoyl chloride, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Linear Formula:
C10H13O3Cl
CAS Number:
39637-74-6
Molecular Weight:
216.66
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
24853548
EC Number:
254-552-4
Beilstein/REAXYS Number:
3590860
MDL number:
MFCD00135626
Assay:
98%

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

(1S)-(−)-Camphanic chloride, 98%

InChI key

PAXWODJTHKJQDZ-VHSXEESVSA-N

InChI

1S/C10H13ClO3/c1-8(2)9(3)4-5-10(8,6(11)12)14-7(9)13/h4-5H2,1-3H3/t9-,10+/m0/s1

SMILES string

CC1(C)[C@@]2(C)CC[C@@]1(OC2=O)C(Cl)=O

assay

98%

optical activity

[α]23/D −18±1°, c = 2 in dioxane

mp

71-73 °C (lit.)

functional group

acyl chloride
ester

storage temp.

2-8°C

Quality Level

200

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

(1S)-(-)-Camphanic chloride is a chiral derivatizing agent. It can be prepared by reacting (-)-(1S,4R)-camphanic acid with thionyl chloride.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
BCCN6662
BCCN2407
BCCM2397
BCCB0598
BCBK1488V

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Chiral separations of ?-blocking drug substances using derivatization with chiral reagents and normal-phase high-performance liquid chromatography.
Olsen L, et al.
Journal of Chromatography A, 636(2), 231-241 (1993)
(-)-(1S, 4R)-Camphanoyl Chloride.
Gerlach H, et al.
Organic Syntheses, 71, 48-48 (1993)
M Ruud-Christensen et al.
Journal of chromatography, 491(2), 355-366 (1989-07-21)
A reversed-phase high-performance liquid chromatographic assay has been developed for determination of (R)-(--)-and (S)-(+)-proxyphylline in human plasma. The procedure is based on liquid-solid extraction of proxyphylline from plasma followed by derivatization of extracted proxyphylline with (--)-camphanoyl chloride. The ratio between
The determination of the absolute configurations of diastereomers of (S)-camphanoyl 3-hydroxy-5-oxohexanoic acid derivatives by X-ray crystallography.
Kwai-Ming Cheung et al.
Angewandte Chemie (International ed. in English), 41(7), 1198-1202 (2002-12-20)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service