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About This Item
Linear Formula:
[CH3COCH=C(O-)CH3]2MoO2
CAS Number:
Molecular Weight:
326.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
241-522-0
MDL number:
Product Name
Bis(acetylacetonato)dioxomolybdenum(VI),
form
powder
Quality Level
reaction suitability
core: molybdenum, reagent type: catalyst
mp
184 °C (dec.) (lit.)
storage temp.
2-8°C
SMILES string
CC(=O)\C=C(\C)O[Mo](=O)(=O)O\C(C)=C/C(C)=O
InChI
1S/2C5H8O2.Mo.2O/c2*1-4(6)3-5(2)7;;;/h2*3,6H,1-2H3;;;/q;;+2;;/p-2/b2*4-3-;;;
InChI key
SKMUJBBRXZPAJY-VGKOASNMSA-L
General description
Bis(acetylacetonato)dioxomolybdenum(VI) is used as a starting material and catalyst for oxidative transformation reactions.
Application
Bis(acetylacetonato)dioxomolybdenum(VI) can be used:
- As a starting material to synthesize dioxomolybdenum(VI) Schiff base complexes, applicable as catalysts in the oxidation of alcohols using H2O2.
- To prepare graphene oxide supported heterogeneous molybdenum catalysts for epoxidation of olefins.
- As a catalyst in the etherification and thio-etherification reactions of thiols and alcohols.
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Dinuclear and polynuclear dioxomolybdenum (VI) Schiff base complexes: synthesis, structural elucidation, spectroscopic characterization, electrochemistry and catalytic property
Ngan NK, et al.
Polyhedron, 33(1), 235-251 (2012)
Synthesis, structures, electrochemical studies and antioxidant activities of cis-dioxomolybdenum (VI) complexes of the new bisthiocarbohydrazones
Kaya Y, et al.
Journal of Molecular Structure, 1102, 17-126 (2015)
Jie Wang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(51), 11841-11850 (2020-05-28)
Pyrite FeS2 as a high-capacity electrode material for lithium-ion batteries (LIBs) is hindered by its unstable cycling performance owing to the large volume change and irreversible phase segregation from coarsening of Fe. Here, the beneficial microstructure evolution in MoS2 -modified
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 227749-50G | 04061838780935 |
| 227749-10G | 04061838780928 |

