Skip to Content
Merck
CN

227749

Bis(acetylacetonato)dioxomolybdenum(VI)

powder

Synonym(s):

MoO2(acac)2, Molybdenum diacetylacetonate dioxide, Molybdenum dioxide bis(acetylacetonate), Molybdenum dioxydiacetylacetonate, Molybdenyl acetylacetonate

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Linear Formula:
[CH3COCH=C(O-)CH3]2MoO2
CAS Number:
Molecular Weight:
326.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
241-522-0
MDL number:
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist


Product Name

Bis(acetylacetonato)dioxomolybdenum(VI),

form

powder

Quality Segment

reaction suitability

core: molybdenum, reagent type: catalyst

mp

184 °C (dec.) (lit.)

storage temp.

2-8°C

SMILES string

CC(=O)\C=C(\C)O[Mo](=O)(=O)O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Mo.2O/c2*1-4(6)3-5(2)7;;;/h2*3,6H,1-2H3;;;/q;;+2;;/p-2/b2*4-3-;;;

InChI key

SKMUJBBRXZPAJY-VGKOASNMSA-L

General description

Bis(acetylacetonato)dioxomolybdenum(VI) is used as a starting material and catalyst for oxidative transformation reactions.

Application

Bis(acetylacetonato)dioxomolybdenum(VI) can be used:
  • As a starting material to synthesize dioxomolybdenum(VI) Schiff base complexes, applicable as catalysts in the oxidation of alcohols using H2O2.
  • To prepare graphene oxide supported heterogeneous molybdenum catalysts for epoxidation of olefins.
  • As a catalyst in the etherification and thio-etherification reactions of thiols and alcohols.



Pictograms

Health hazardExclamation mark

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Gloves



Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library