227994
Bis(dibenzylideneacetone)palladium(0)
powder
Synonym(s):
Palladium(0) bis(dibenzylideneacetone), Pd(dba)2
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About This Item
Product Name
Bis(dibenzylideneacetone)palladium(0),
form
powder
Quality Level
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
SMILES string
[Pd].O=C(/C=C/c1ccccc1)\C=C\c2ccccc2.O=C(/C=C/c3ccccc3)\C=C\c4ccccc4
InChI
1S/2C17H14O.Pd/c2*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;/h2*1-14H;/b2*13-11+,14-12+;
InChI key
UKSZBOKPHAQOMP-SVLSSHOZSA-N
General description
Application
- Synthesis of isomeric 2-aryl-2,5-dihydrofurans, via Heck coupling of aryl bromides with alkenes using neopentyl phosphine ligands.
- Heck reaction of benzyl trifluoroacetate and 2,3-dihydrofuran phosphoramidite ligand.
- Allylation of stabilized anions.
- Cross coupling of allyl, alkenyl and aryl halides with organostannanes.
- Cross coupling of vinyl halides with alkenyl zinc species.
- Carbonylation of alkenyl and aryl halides.
- Employed with cyclic thiourea ligands in an efficient aerobic oxidation of alcohols to aldehydes and ketones.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 227994-500MG | 04061838781086 |
| 227994-2G | 04061838781079 |
| 227994-50G | 04061833410370 |
| 227994-5G | 04061838781093 |