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Merck
CN

229024

R-Alpine-Hydride®

0.5 M in THF

Synonym(s):

Lithium B-isopinocampheyl-9-borabicyclo[3.3.1]nonyl hydride solution

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About This Item

Empirical Formula (Hill Notation):
C18H32BLi
CAS Number:
Molecular Weight:
266.20
UNSPSC Code:
12352000
PubChem Substance ID:
MDL number:
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InChI

1S/C18H32B.Li/c1-12-16-10-13(18(16,2)3)11-17(12)19-14-6-4-7-15(19)9-5-8-14;/h12-17,19H,4-11H2,1-3H3;/q-1;+1/t12-,13+,14-,15+,16-,17-,19?;/m1./s1

SMILES string

[Li+].C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)[BH-]3[C@@H]4CCC[C@H]3CCC4

InChI key

JBOSJEWMOTWSER-ZEBZFEJDSA-N

form

liquid

optical activity

[α]20/D −8.5°

concentration

0.5 M in THF

density

0.919 g/mL at 25 °C (lit.)

Other Notes

Made from (+)-α-pinene

Legal Information

Alpine-Hydride is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

target_organs

Respiratory system

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

1.4 °F

flash_point_c

-17 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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