23030
1-Chloroethyl ethyl carbonate
≥98.0% (GC)
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About This Item
Linear Formula:
CH3CH2OCOOCHClCH3
CAS Number:
Molecular Weight:
152.58
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
256-832-1
Beilstein/REAXYS Number:
3536477
MDL number:
Product Name
1-Chloroethyl ethyl carbonate, ≥98.0% (GC)
InChI key
YVRGKFXJZCTTRB-UHFFFAOYSA-N
InChI
1S/C5H9ClO3/c1-3-8-5(7)9-4(2)6/h4H,3H2,1-2H3
SMILES string
CCOC(=O)OC(C)Cl
assay
≥98.0% (GC)
refractive index
n20/D 1.413
bp
159-161 °C (lit.)
density
1.136 g/mL at 20 °C (lit.)
storage temp.
2-8°C
Other Notes
Protecting group reagent for introducing the acid-cleavable 1-(ethoxycarbonyloxy)ethyl group in acids, phenols and amines; in pharmaceuticals, the 1-(ethoxycarbonyloxy)ethyl derivatives serve as masked products which are hydrolyzed in plasma
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
149.0 °F - closed cup
flash_point_c
65 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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C M Svahn et al.
Journal of medicinal chemistry, 29(4), 448-453 (1986-04-01)
Derivatives of the antifibrinolytic drug tranexamic acid [trans-4-(aminomethyl)cyclohexanecarboxylic acid] containing one or two tranexamic acid moieties were synthesized. Most of the derivatives have good stability in acidic and neutral solutions but are easily hydrolyzed in plasma. By measuring the amount
G. Barcelo et al.
Synthesis, 627-627 (1986)
T Nishimura et al.
The Journal of antibiotics, 40(1), 81-90 (1987-01-01)
Orally active 1-(alkyl substituted cyclohexyloxycarbonyloxy)alkyl ester prodrugs (9b-h) of 7 beta-[2-(2-aminothiazol-4-yl)acetamido]-3- [[[1-(2-dimethylaminoethyl)-1H-tetrazol-5-yl]thio]-methyl]ceph+ ++-3- em-4-carboxylic acid (cefotiam, CTM) have been studied as well as the thia (9i) and aza (9j) analogs. These represent derivatives of the 1-(cyclohexylacetoxy)ethyl ester (2) of CTM.
Tigist Y Tamir et al.
Journal of cell science, 133(14) (2020-06-18)
Nuclear factor erythroid 2-related factor 2 (NFE2L2, also known as NRF2) is a transcription factor and master regulator of cellular antioxidant response. Aberrantly high NRF2-dependent transcription is recurrent in human cancer, but conversely NRF2 activity diminishes with age and in
Caiyun G Li et al.
Cell reports, 26(5), 1333-1343 (2019-01-31)
Using proteomic approaches, we uncovered a DNA damage response (DDR) function for peroxisome proliferator activated receptor γ (PPARγ) through its interaction with the DNA damage sensor MRE11-RAD50-NBS1 (MRN) and the E3 ubiquitin ligase UBR5. We show that PPARγ promotes ATM
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