23030
1-Chloroethyl ethyl carbonate
≥98.0% (GC)
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About This Item
Linear Formula:
CH3CH2OCOOCHClCH3
CAS Number:
Molecular Weight:
152.58
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
256-832-1
Beilstein/REAXYS Number:
3536477
MDL number:
assay
≥98.0% (GC)
refractive index
n20/D 1.413
bp
159-161 °C (lit.)
density
1.136 g/mL at 20 °C (lit.)
storage temp.
2-8°C
SMILES string
CCOC(=O)OC(C)Cl
InChI
1S/C5H9ClO3/c1-3-8-5(7)9-4(2)6/h4H,3H2,1-2H3
InChI key
YVRGKFXJZCTTRB-UHFFFAOYSA-N
Other Notes
Protecting group reagent for introducing the acid-cleavable 1-(ethoxycarbonyloxy)ethyl group in acids, phenols and amines; in pharmaceuticals, the 1-(ethoxycarbonyloxy)ethyl derivatives serve as masked products which are hydrolyzed in plasma
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
149.0 °F - closed cup
flash_point_c
65 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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C M Svahn et al.
Journal of medicinal chemistry, 29(4), 448-453 (1986-04-01)
Derivatives of the antifibrinolytic drug tranexamic acid [trans-4-(aminomethyl)cyclohexanecarboxylic acid] containing one or two tranexamic acid moieties were synthesized. Most of the derivatives have good stability in acidic and neutral solutions but are easily hydrolyzed in plasma. By measuring the amount
T Nishimura et al.
The Journal of antibiotics, 40(1), 81-90 (1987-01-01)
Orally active 1-(alkyl substituted cyclohexyloxycarbonyloxy)alkyl ester prodrugs (9b-h) of 7 beta-[2-(2-aminothiazol-4-yl)acetamido]-3- [[[1-(2-dimethylaminoethyl)-1H-tetrazol-5-yl]thio]-methyl]ceph+ ++-3- em-4-carboxylic acid (cefotiam, CTM) have been studied as well as the thia (9i) and aza (9j) analogs. These represent derivatives of the 1-(cyclohexylacetoxy)ethyl ester (2) of CTM.
G. Barcelo et al.
Synthesis, 627-627 (1986)