23215
1-Naphthyl chloroformate
≥98.0% (GC)
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About This Item
Empirical Formula (Hill Notation):
C11H7ClO2
CAS Number:
Molecular Weight:
206.63
EC Number:
223-168-9
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
512216
MDL number:
InChI key
JRUFQZPDRRGHEF-UHFFFAOYSA-N
InChI
1S/C11H7ClO2/c12-11(13)14-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
SMILES string
ClC(=O)Oc1cccc2ccccc12
assay
≥98.0% (GC)
refractive index
n20/D 1.598
density
1.273 g/mL at 20 °C (lit.)
storage temp.
2-8°C
Quality Level
Application
1-Naphthyl chloroformate was used in preparation of:
- 4-benzyl-2-(4-methoxyphenyl)oxazol-5-yl naphthalen-1-ylcarbonate
- naphthalen-1-yl 4-benzyl-2-(4-methoxyphenyl)-5-oxo-4,5-dihydrooxazole-4-carboxylate
- 2-(4-methoxyphenyl)-4-methyloxazol-5-yl naphthalen-1-ylcarbonate
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
257.0 °F - closed cup
flash_point_c
125 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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Craig D Campbell et al.
Organic & biomolecular chemistry, 9(11), 4205-4218 (2011-04-21)
The O- to C-carboxyl transfer of oxazolyl carbonates promoted by triazolinylidenes, generated in situ with NEt(3), shows a markedly different rate and chemoselectivity profile to the same reaction promoted by triazolinylidenes generated using KHMDS. The mechanism of these pathways has
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