232173
S,S-Diphenylsulfilimine monohydrate
97%
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About This Item
Linear Formula:
(C6H5)2S=NH · H2O
CAS Number:
Molecular Weight:
219.30
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2043848
Assay:
97%
Form:
powder
InChI
1S/C12H11NS.H2O/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12;/h1-10,13H;1H2
SMILES string
[H]O[H].N=S(c1ccccc1)c2ccccc2
InChI key
YLGYIQQZVOCMDO-UHFFFAOYSA-N
assay
97%
form
powder
functional group
thioether
General description
Kinetics and mechanism of reaction of S,S-diphenylsulfilimine with 1-fluoro-2,4-dinitrobenzene, 1-chloro-2,4-dinitrobenzene, 2-chloro-3-nitropyridine, 2-chloro-5-nitropyridine and 2-chloro-3,5-dinitropyridine has been investigated.
Application
S,S-Diphenylsulfilimine monohydrate is a versatile synthetic tool and has been used in preparation of:
- N-(5-nitrosouracil-6-yl)sulfilimines
- N-(1,3-dimethyl-6-uracilyl)-S,S-diphenylsulfilimines
- N-(5-formyl-1,3-dimethyl-6-uracilyl)-S,S-diphenylsulfilimines
Storage Class
11 - Combustible Solids
wgk
WGK 3
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Kinetics and mechanism of the reaction of S, S-diphenylsulfilimine with a series of aryl halides.
Sandall JB and Steel ND.
J. Chem. Soc. Perkin Trans. II, 3, 513-516 (1997)
Ring closure reactions of ?-nitroso-, ?-acyl-, and ?-thiocarbamoyl-a, ?-unsaturated sulfilimines. Synthesis of [1, 2, 5] oxadiazolo [3, 4-d]-, isoxazolo [3, 4-d]-, and isothiazolo [3, 4-d] pyrimidine derivatives from uracils.
Matsumoto N and Takahashi M.
Tetrahedron, 58(50), 10073-10079 (2002)
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