232483
Diethyl 3-oxopimelate
Synonym(s):
3-Oxoheptanedioic acid diethyl ester, Diethyl 3-oxoheptanedioate
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About This Item
Linear Formula:
C2H5OCOCH2CH2CH2COCH2COOC2H5
CAS Number:
Molecular Weight:
230.26
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
254-912-0
Beilstein/REAXYS Number:
1791883
MDL number:
InChI key
RTMQRCLOAACETL-UHFFFAOYSA-N
InChI
1S/C11H18O5/c1-3-15-10(13)7-5-6-9(12)8-11(14)16-4-2/h3-8H2,1-2H3
SMILES string
CCOC(=O)CCCC(=O)CC(=O)OCC
form
liquid
refractive index
n20/D 1.447 (lit.)
bp
130-132 °C/0.5 mmHg (lit.)
density
1.084 g/mL at 25 °C (lit.)
functional group
ester
ketone
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Application
Diethyl 3-oxopimelate was used in synthesis of 2′-, 5′-and centrally tethered C-branched spermine oligo-DNAs on the solid support.
Reactant involved in:
- Regioselective one-pot synthesis of 1,3,4-trisubstituted-1H-pyrazoles
- Synthesis of lupinine via stereoselective multicomponent condensation
- Solvent-free condensation of β-keto esters with amidoximes
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
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The chemistry of C-branched spermine tethered oligo-DNAs and their properties in forming duplexes and triplexes.
Sund C, et al.
Nucleosides, nucleotides & nucleic acids, 16(5-6), 755-760 (1997)
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