232599
Ethyl methoxyacetate
97%
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About This Item
Linear Formula:
CH3OCH2COOC2H5
CAS Number:
Molecular Weight:
118.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
223-521-7
Beilstein/REAXYS Number:
1744761
MDL number:
Product Name
Ethyl methoxyacetate, 97%
InChI key
JLEKJZUYWFJPMB-UHFFFAOYSA-N
InChI
1S/C5H10O3/c1-3-8-5(6)4-7-2/h3-4H2,1-2H3
SMILES string
CCOC(=O)COC
assay
97%
form
liquid
refractive index
n20/D 1.401 (lit.)
bp
44-45.5 °C/9 mmHg (lit.)
density
1.007 g/mL at 25 °C (lit.)
functional group
ester
ether
Quality Level
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Application
Ethyl methoxyacetate was used:
- as acyl donor during the preparation of enantiomers of several phenylethylamines
- as acylation reagent for the aminolysis of 1-phenylethanamine
- in an industrial, lipase-catalysed kinetic resolution of primary amine
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Lourdes Muñoz et al.
Organic & biomolecular chemistry, 9(23), 8171-8177 (2011-10-06)
Both enantiomers of several phenylethylamines, structurally related to amphetamine, have been prepared in good yields and excellent enantiomeric purity by enzymatic kinetic resolution using CAL-B and ethyl methoxyacetate as the acyl donor. In the case of the 4-hydroxyderivative of amphetamine
Ulf Hanefeld
Organic & biomolecular chemistry, 1(14), 2405-2415 (2003-09-06)
Commonly, hydrolase-catalysed reactions are used for kinetic resolutions of alcohols, amines and acids. Only a few applications in total syntheses have been described. Most of these examples are for the synthesis of amides and peptides. Here, the synthesis of all
Saija Sirén et al.
Molecules (Basel, Switzerland), 25(4) (2020-02-23)
The enantiomers of aromatic 4-dibenzocyclooctynol (DIBO), used for radiolabeling and subsequent conjugation of biomolecules to form radioligands for positron emission tomography (PET), were separated by kinetic resolution using lipase A from Candida antarctica (CAL-A). In optimized conditions, (R)-DIBO [(R)-1, ee
C Saito et al.
Biotechnic & histochemistry : official publication of the Biological Stain Commission, 74(1), 40-48 (1999-04-06)
An in situ hybridization procedure resulting in both high resolution and sensitivity was established by using the removable methyl methacrylate resin, Technovit 9100. Young bicellular pollen of tobacco (Nicotiana tabacum L. SR-1) was embedded in Technovit 9100 resin and sectioned.
A Basler
Mutation research, 174(1), 11-13 (1986-05-01)
Chinese hamsters were exposed to acetone, methyl ethyl ketone, ethyl acetate and 2-methoxy ethyl acetate, known to be strong inducers of aneuploidy in the yeast Saccharomyces cerevisiae. All solvents yielded negative results in the micronucleus test, whereas the vinca alkaloid
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