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233595

2,6-Diphenylphenol

Name: 2,6-Diphenylphenol
Brand: ALDRICH

98%

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About This Item

Linear Formula:

(C₆H₅)₂C₆H₃OH

CAS Number:

2432-11-3

Molecular Weight:

246.30

NACRES:

NA.22

PubChem Substance ID:

24853986

UNSPSC Code:

12352100

EC Number:

219-401-9

MDL number:

MFCD00009716

Assay:

98%

Form:

solid

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Properties

Quality Level

100

assay

98%

form

solid

mp

101-103 °C (lit.)

functional group

phenyl

SMILES string

Oc1c(cccc1-c2ccccc2)-c3ccccc3

InChI

1S/C18H14O/c19-18-16(14-8-3-1-4-9-14)12-7-13-17(18)15-10-5-2-6-11-15/h1-13,19H

InChI key

ATGFTMUSEPZNJD-UHFFFAOYSA-N

Description

General description

2,6-Diphenylphenol reacts with with (n)BuLi, NaH, KH, or Rb or Cs metal in benzene to yield the solvent-free complexes [M(OAr)]_x.

Application

2,6-Diphenylphenol has been used:

as ligand during the synthesis of reduced coordination (less than 6), unchelated manganese oxygen cluster systems
in the preparation of derivatives of pyrazine-2,3-dicarbonitrile, precursor required for the synthesis of octaazaphthalocyanine (AzaPc) derivatives

pictograms

GHS09

signalword

Warning

hcodes

H410

pcodes

P273 - P391 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis, structure, and magnetic studies of manganese-oxygen clusters of reduced coordination number, featuring an unchelated, 5-coordinate octanuclear manganese cluster with water-derived oxo ligands.

Sandeep K Kondaveeti et al.

Inorganic chemistry, 51(19), 10095-10104 (2012-09-06)

The synthesis of reduced coordination (less than 6), unchelated manganese oxygen cluster systems is described. Addition of phenols to Mn(NR(2))(2) (R = SiMe(3)) results in protolytic amide ligand replacement, and represents the primary entry into the described chemistry. Addition of

Synthesis of group 1 metal 2,6-diphenylphenoxide complexes [M(OC6H3Ph2-2,6)] (M = Li, Na, K, Rb, Cs) and structures of the solvent-free complexes [Rb(OC6H3Ph2-2,6)]x and [Cs(OC6H3Ph2-2,6)x: one-dimensional extended arrays of metal aryloxides.

Charles S Weinert et al.

Inorganic chemistry, 42(19), 6089-6094 (2003-09-16)

Reaction of 2,6-diphenylphenol (HOC(6)H(3)Ph(2)-2,6) with (n)BuLi, NaH, KH, or Rb or Cs metal in benzene gives the solvent-free complexes [M(OAr)]x in excellent yield. The complex [Rb(OC(6)H(3)Ph(2)-2,6)](x)() exhibits a ladderlike structure in the solid state with triply bridging oxygen atoms and

Clathrate formation from octaazaphthalocyanines possessing bulky phenoxyl substituents: a new cubic crystal containing solvent-filled, nanoscale voids.

Saad Makhseed et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 14(16), 4810-4815 (2008-05-01)

The synthesis of octaazaphthalocyanine (AzaPc) derivatives, with bulky phenoxyl substituents placed at eight peripheral positions and containing either H(+), Ni(2+) or Zn(2+) ions in their central cavity, is described. The required precursors, derivatives of pyrazine-2,3-dicarbonitrile, were prepared using a nucleophilic

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Global Trade Item Number

SKU	GTIN
233595-1G	04061826279205
233595-25G	04061832880013
233595-5G	04061838784063