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Merck
CN

233803

3-(Trimethylsilyl)-1-propanol

97%

Synonym(s):

1-(Trimethylsilyl)-3-propanol, 3-(Trimethylsilyl)-1-propanol, 3-(Trimethylsilyl)propanol, 3-(Trimethylsilyl)propyl alcohol, 3-Hydroxypropyltrimethylsilane

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About This Item

Linear Formula:
(CH3)3Si(CH2)3OH
CAS Number:
2917-47-7
Molecular Weight:
132.28
MDL number:
MFCD00009712
UNSPSC Code:
12352100
PubChem Substance ID:
24854012
NACRES:
NA.22

Key Documents

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Quality Level

100

Assay

97%

refractive index

n20/D 1.428 (lit.)

bp

111-112 °C/96 mmHg (lit.)

density

0.832 g/mL at 25 °C (lit.)

functional group

hydroxyl

SMILES string

C[Si](C)(C)CCCO

InChI

1S/C6H16OSi/c1-8(2,3)6-4-5-7/h7H,4-6H2,1-3H3

InChI key

YNUUCDHAZGAVEZ-UHFFFAOYSA-N

Related Categories

Application

3-(Trimethylsilyl)-1-propanol has been used in:
  • the synthesis of telechelic oligomers via atom transfer radical polymerization (ATRP) of styrene
  • the preparation of the β-seleno-γ-silyl alcohols

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

127.4 °F - closed cup

Flash Point(C)

53 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
SHBQ3648
61407EM
19425BA
16617MO
09223AO

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Silicon-controlled rearrangement versus Krief-Reich reaction in ?-seleno-?-silyl alcohols: a new stereoselective synthesis of terminally-substituted allylsilanes.
Sarkar TK and Ghosh SK.
Tetrahedron Letters, 28(18), 2061-2064 (1987)
Synthesis of Telechelic Oligomers via Atom Transfer Radical Polymerization, 1.
Otazaghine B, et al.
Macromolecular Chemistry and Physics, 205(2), 154-164 (2004)
Adam Czajka et al.
Physical chemistry chemical physics : PCCP, 19(35), 23869-23877 (2017-07-21)
Presented here are the results for a novel class of hydrocarbon surfactants, termed trimethylsilyl hedgehogs (TMS-hedgehogs), due to the presence of silicon in the tails. By comparing the surface properties of these hybrid hedgehogs to purely hydrocarbon equivalents, links between

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