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About This Item
Linear Formula:
BrCH2CO2Si(CH3)3
CAS Number:
Molecular Weight:
211.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
242-165-3
Beilstein/REAXYS Number:
1927560
MDL number:
Assay:
98%
Form:
liquid
vapor density
>1 (vs air)
Quality Segment
assay
98%
form
liquid
refractive index
n20/D 1.442 (lit.)
bp
57-58 °C/9 mmHg (lit.)
density
1.284 g/mL at 25 °C (lit.)
SMILES string
C[Si](C)(C)OC(=O)CBr
InChI
1S/C5H11BrO2Si/c1-9(2,3)8-5(7)4-6/h4H2,1-3H3
InChI key
ZCHHFMWUDHXPFN-UHFFFAOYSA-N
Application
Trimethylsilyl bromoacetate has been used:
- in the preparation of new imidazolium salts functionalized with the trimethylsilyl ester group
- as alkylating agent in the synthesis of succinate fragment of pantocin B (antibiotic natural product)
- in the synthesis of taxol derivatives tethered at C2′ and C-7 to glutamate and folate
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
116.6 °F - closed cup
flash_point_c
47 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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