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237698

(S)-(+)-2-Butanol

Name: (<I>S</I>)-(+)-2-Butanol
Brand: ALDRICH

99%

Synonym(s):

(S)-(+)-sec-Butyl alcohol

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About This Item

Linear Formula:

C₂H₅CH(OH)CH₃

CAS Number:

4221-99-2

Molecular Weight:

74.12

UNSPSC Code:

12352001

NACRES:

NA.22

PubChem Substance ID:

24854264

EC Number:

224-168-1

Beilstein/REAXYS Number:

1718763

MDL number:

MFCD00064281

Assay:

99%

Form:

liquid

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Properties

vapor density

2.6 (vs air)

Quality Level

100

vapor pressure

12.5 mmHg ( 20 °C)

assay

99%

form

liquid

optical activity

[α]20/D +13°, neat

autoignition temp.

761 °F

expl. lim.

9.8 %

refractive index

n20/D 1.397 (lit.)

bp

99-100 °C (lit.)

density

0.803 g/mL at 25 °C (lit.)

functional group

hydroxyl

SMILES string

CC[C@H](C)O

InChI

1S/C4H10O/c1-3-4(2)5/h4-5H,3H2,1-2H3/t4-/m0/s1

InChI key

BTANRVKWQNVYAZ-BYPYZUCNSA-N

Description

Application

(S)-(+)-2-Butanol can be used:

To synthesize chiral asymmetric perylene diimides (PDI) that spontaneously self-assemble into one-handed nanotubes that are photoconductive or fluorescent in nature.
To synthesize bulky chiral vinyl monomers that can be radically polymerized to helical polymers with an excess screw sense.
As chiral solvent to study excited state photo transfer of the photoacid, 5,8-dicyano-2-naphthol (DCN2) in chiral environment.

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pictograms

GHS02,GHS07

signalword

Warning

hcodes

H226,H319,H335,H336

pcodes

P210 - P233 - P240 - P241 - P242 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

target_organs

Central nervous system, Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

75.2 °F - closed cup

flash_point_c

24 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Excited-state proton transfer in chiral environments. 1. Chiral solvents.

Solntsev KM, et al.

Journal of the American Chemical Society, 124(31), 9046-9047 (2002)

Highly fluorescent one-handed nanotubes assembled from a chiral asymmetric perylene diimide.

Ma X , et al.

Chemical Communications (Cambridge, England), 51(20), 4231-4233 (2015)

Synthesis and characterization of optically active helical vinyl polymers via free radical polymerization.

Zhi J, et al.

Journal of Polymer Science Part A: Polymer Chemistry, 47(9), 2408-2421 (2009)

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Global Trade Item Number

SKU	GTIN
237698-1G	04061838786258
237698-10G	04061837639333