Skip to Content
Merck
CN

237744

(S)-(+)-1,2-Isopropylideneglycerol

98%, optical purity ee: 99% (GLC)

Synonym(s):

(S)-(+)-2,2-Dimethyl-1,3-dioxolane-4-methanol, 1,2-Isopropylidene-sn-glycerol, D-α,β-Isopropylideneglycerol, D-(+)-Solketal, D-1,2-O-isopropylidene-sn-glycerol

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Empirical Formula (Hill Notation):
C6H12O3
CAS Number:
22323-82-6
Molecular Weight:
132.16
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
24854267
EC Number:
244-910-8
Beilstein/REAXYS Number:
80118
MDL number:
MFCD00063239

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

(S)-(+)-1,2-Isopropylideneglycerol, 98%, optical purity ee: 99% (GLC)

InChI key

RNVYQYLELCKWAN-YFKPBYRVSA-N

InChI

1S/C6H12O3/c1-6(2)8-4-5(3-7)9-6/h5,7H,3-4H2,1-2H3/t5-/m0/s1

SMILES string

CC1(C)OC[C@H](CO)O1

assay

98%

form

liquid

optical activity

[α]20/D +13.5°, neat

optical purity

ee: 99% (GLC)

refractive index

n20/D 1.434 (lit.)

bp

82-83 °C/14 mmHg (lit.)

density

1.07 g/mL at 25 °C (lit.)

functional group

ether
hydroxyl
ketal

storage temp.

2-8°C

Quality Level

200

Related Categories

Application

(S)-(+)-1,2-Isopropylideneglycerol may be used as a calibration standard during the GC analysis of the solketal yield and glycerol conversion in the ketalization reaction of glycerol and acetone. It may also be used to synthesize 1,2-dipalmitoyl-3-benzyl-sn-glycerol and 1-O-(Z)-octadecenyl-sn-glycerol, an intermediate for plasmalogen synthesis.
Used in a synthesis of a chiral allylic triol via extrusion of SO2 from an α,β-epoxysulfone.

General description

(S)-(+)-1,2-Isopropylideneglycerol is a key building block for the synthesis of glycerides and of phosphoglycerides.

Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

194.0 °F - closed cup

flash_point_c

90 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

新产品
This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
BCBZ6003
BCBZ5709
BCBW7478
SHBJ2063
SHBJ0793

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Synthesis of Plasmalogen via 2, 3-Bis-O-(4 '-methoxybenzyl)-sn-glycerol.
Qin D, et al.
Journal of the American Chemical Society, 121(4), 662-668 (1999)
European Journal of Organic Chemistry, 1740-1740 (2006)
[58] Synthesis of labeled phospholipids in high yield.
Eibl H, et al.
Methods in Enzymology, 98, 623-632 (1983)
An improved method for the preparation of 1, 2-isopropylidene-sn-glycerol.
Eibl H.
Chemistry and Physics of Lipids, 28(1), 1-5 (1981)
Thermodynamic and kinetic studies of a catalytic process to convert glycerol into solketal as an oxygenated fuel additive.
Nanda MR, et al.
Fuel: The Science and Technology of Fuel and Energy, 117, 470-477 (2014)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service