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238139

1-Iodonaphthalene

Name: 1-Iodonaphthalene
Brand: ALDRICH

97%

Synonym(s):

1-Naphthyl iodide

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₇I

CAS Number:

90-14-2

Molecular Weight:

254.07

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24854293

EC Number:

201-968-9

Beilstein/REAXYS Number:

1906415

MDL number:

MFCD00003876

Assay:

97%

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Properties

Quality Level

200

assay

97%

refractive index

n20/D 1.701 (lit.)

bp

163-165 °C/15 mmHg (lit.)

density

1.74 g/mL at 25 °C (lit.)

functional group

iodo

SMILES string

Ic1cccc2ccccc12

InChI

1S/C10H7I/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H

InChI key

NHPPIJMARIVBGU-UHFFFAOYSA-N

Description

General description

Ultrafast relaxation of 1-iodonaphthalene has been studied by time-resolved femtosecond pump-probe mass spectrometry. 1-Iodonaphthalene undergoes Pd catalyzed cross-coupling reaction (Stille reaction) with 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine to afford 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319

pcodes

P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Femtosecond time-resolved photophysics and photodissociation dynamics of 1-iodonaphthalene.

Raul Montero et al.

Physical chemistry chemical physics : PCCP, 12(28), 7988-7993 (2010-06-03)

The ultrafast relaxation of 1-iodonaphthalene, with particular attention to the dissociation channels, has been studied by time-resolved femtosecond pump-probe mass spectrometry following excitation at 267 and 317 nm. The measured transients for the parent ion and the isobaric fragments, iodine

A novel approach to the synthesis of 6-substituted uracils in three-step, one-pot reactions.

Javier I Bardagí et al.

The Journal of organic chemistry, 73(12), 4491-4495 (2008-05-21)

From the commercial 6-chloro-2,4-dimethoxypyrimidine (1) and by a photostimulated reaction with Me(3)Sn(-) ions, 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine (2) was obtained in 95% yield. By the cross-coupling reaction of 2 with 1-iodonaphthalene as electrophile catalyzed by Pd (Stille reaction), 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine (9) was obtained in

Global Trade Item Number

SKU	GTIN
238139-50G	04061838786661
238139-10G	04061838786654