238244
Iodocyclohexane
98%
Synonym(s):
Cyclohexyl iodide
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About This Item
Empirical Formula (Hill Notation):
C6H11I
CAS Number:
Molecular Weight:
210.06
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-957-8
Beilstein/REAXYS Number:
1900797
MDL number:
Assay:
98%
Form:
liquid
Product Name
Iodocyclohexane, 98%
InChI key
FUCOMWZKWIEKRK-UHFFFAOYSA-N
InChI
1S/C6H11I/c7-6-4-2-1-3-5-6/h6H,1-5H2
SMILES string
IC1CCCCC1
assay
98%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.5441 (lit.)
bp
80-81 °C/20 mmHg (lit.)
density
1.624 g/mL at 25 °C (lit.)
functional group
iodo
storage temp.
2-8°C
Quality Level
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Application
Iodocyclohexane has been employed as reagent in demethylation of aryl methyl ethers in DMF under reflux condition.
General description
The photodissociation dynamics of iodocyclohexane has been studied using velocity map imaging. Nickel catalyzed coupling of iodocyclohexane with 1-octyne has been investigated.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
158.0 °F - closed cup
flash_point_c
70 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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An efficient method for demethylation of aryl methyl ethers.
Zuo L, et al.
Tetrahedron Letters, 49(25), 4054-4056 (2008)
Jun Yi et al.
Angewandte Chemie (International ed. in English), 52(47), 12409-12413 (2013-10-12)
A nicked reaction: The title reaction of terminal alkynes with non-activated secondary alkyl iodides and bromides was accomplished for the first time. This reaction provides a new and practical approach for the synthesis of substituted alkynes (see scheme; cod=cyclo-1,5-octadiene).
D K Zaouris et al.
The Journal of chemical physics, 135(9), 094312-094312 (2011-09-15)
The photodissociation dynamics of iodocyclohexane has been studied using velocity map imaging following excitation at many wavelengths within its A-band (230 ≤ λ ≤ 305 nm). This molecule exists in two conformations (axial and equatorial), and one aim of the
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