238325
Allyl iodide
98%
Synonym(s):
3-Iodo-1-propene
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About This Item
Linear Formula:
CH2=CHCH2I
CAS Number:
Molecular Weight:
167.98
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-130-4
Beilstein/REAXYS Number:
1697594
MDL number:
Assay:
98%
Form:
liquid
Quality Level
assay
98%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.554 (lit.)
bp
102-103 °C (lit.)
solubility
alcohol: miscible(lit.), chloroform: miscible(lit.), diethyl ether: miscible(lit.), water: insoluble (practically)(lit.)
density
1.837 g/mL at 25 °C (lit.)
functional group
alkyl halide, iodo
storage temp.
2-8°C
SMILES string
ICC=C
InChI
1S/C3H5I/c1-2-3-4/h2H,1,3H2
InChI key
HFEHLDPGIKPNKL-UHFFFAOYSA-N
General description
The interaction of allyl iodide with MoO3, Bi2O3 and molybdates of Bi, Co and Mg has been studied in the temperature range of 270-480°C.
Application
Allyl iodide has been employed as:
- precursor for generation of allyl radicals to study their recombination in a single pulse shock tube with gas chromatographic measurements
- reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
60.8 °F - closed cup
flash_point_c
16 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Xin Ma et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(25), 6355-6361 (2019-02-28)
Unexpectedly, the 5-dehydroquinoline radical cation was formed in the gas phase from the 5-iodo-8-nitroquinolinium cation upon ion-trap collision-activated dissociation. This reaction involves the cleavage of a nitro group to generate an intermediate monoradical, namely, the 8-dehydro-5-iodoquinolinium cation, followed by rearrangement
Aleksandr Fridlyand et al.
The journal of physical chemistry. A, 117(23), 4762-4776 (2013-05-18)
The recombination and disproportionation of allyl radicals has been studied in a single pulse shock tube with gas chromatographic measurements at 1-10 bar, 650-1300 K, and 1.4-2 ms reaction times. 1,5-Hexadiene and allyl iodide were used as precursors. Simulation of
Tsunehisa Hirashita et al.
Organic & biomolecular chemistry, 5(13), 2154-2158 (2007-06-22)
The successive double allylation of cyclopropenes with allylindium sesquiiodide and allyl iodide proceeded with a cis-addition mode in the presence of other organometallics (e.g. Grignard reagent, cuprate, Et(2)Zn and Et(3)Al), giving the corresponding cis-diallylcyclopropanes in high yields.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 238325-100G | 04061838786852 |
| 238325-25G | 04061838786869 |