241652
1-Bromo-6-chlorohexane
95%
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About This Item
Linear Formula:
Br(CH2)6Cl
CAS Number:
Molecular Weight:
199.52
Beilstein:
1697304
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
95%
form
liquid
refractive index
n20/D 1.481 (lit.)
bp
109-110 °C/2 mmHg (lit.)
density
1.337 g/mL at 25 °C (lit.)
SMILES string
ClCCCCCCBr
InChI
1S/C6H12BrCl/c7-5-3-1-2-4-6-8/h1-6H2
InChI key
JTYUIAOHIYZBPB-UHFFFAOYSA-N
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Application
1-Bromo-6-chlorohexane was used in the synthesis of zinc reagent by reacting with Mg turnings in the presence of ZnCl2 and LiCl.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
213.8 °F - closed cup
Flash Point(C)
101 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Preparation of highly functionalized alkylzinc halides from alkyl bromides using Mg, ZnCl2 and LiCl.
Tobias D Blümke et al.
Chemical communications (Cambridge, England), 46(23), 4082-4084 (2010-04-10)
Alkyl bromides bearing various functional groups are smoothly converted to functionalized alkylzinc reagents by the direct insertion of magnesium in the presence of LiCl and ZnCl(2).
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