241652
1-Bromo-6-chlorohexane
95%
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About This Item
Linear Formula:
Br(CH2)6Cl
CAS Number:
Molecular Weight:
199.52
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
228-555-6
Beilstein/REAXYS Number:
1697304
MDL number:
Assay:
95%
Form:
liquid
InChI key
JTYUIAOHIYZBPB-UHFFFAOYSA-N
InChI
1S/C6H12BrCl/c7-5-3-1-2-4-6-8/h1-6H2
SMILES string
ClCCCCCCBr
assay
95%
form
liquid
bp
109-110 °C/2 mmHg (lit.)
density
1.337 g/mL at 25 °C (lit.)
Application
1-Bromo-6-chlorohexane was used in the synthesis of zinc reagent by reacting with Mg turnings in the presence of ZnCl2 and LiCl.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
213.8 °F - closed cup
flash_point_c
101 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Regulatory Information
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Preparation of highly functionalized alkylzinc halides from alkyl bromides using Mg, ZnCl2 and LiCl.
Tobias D Blümke et al.
Chemical communications (Cambridge, England), 46(23), 4082-4084 (2010-04-10)
Alkyl bromides bearing various functional groups are smoothly converted to functionalized alkylzinc reagents by the direct insertion of magnesium in the presence of LiCl and ZnCl(2).
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