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242403

(Bromomethyl)cyclopropane

97%

Synonym(s):

Cyclopropylmethyl bromide

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About This Item

Linear Formula:
C3H5CH2Br
CAS Number:
7051-34-5
Molecular Weight:
135.00
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24854557
EC Number:
230-331-8
Beilstein/REAXYS Number:
605296
MDL number:
MFCD00001306
Assay:
97%
Form:
liquid
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Quality Segment

assay

97%

form

liquid

refractive index

n20/D 1.457 (lit.)

bp

105-107 °C (lit.)

density

1.392 g/mL at 25 °C (lit.)

functional group

bromo

SMILES string

BrCC1CC1

InChI

1S/C4H7Br/c5-3-4-1-2-4/h4H,1-3H2

InChI key

AEILLAXRDHDKDY-UHFFFAOYSA-N

General description

The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.

Application

(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Codes

H226,H302

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 3

Storage Class

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

105.8 °F

Flash Point (°C)

41 °C

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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