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242403

(Bromomethyl)cyclopropane

Name: (Bromomethyl)cyclopropane
Brand: ALDRICH

97%

Synonym(s):

Cyclopropylmethyl bromide

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About This Item

Linear Formula:

C₃H₅CH₂Br

CAS Number:

7051-34-5

Molecular Weight:

135.00

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24854557

EC Number:

230-331-8

Beilstein/REAXYS Number:

605296

MDL number:

MFCD00001306

Assay:

97%

Form:

liquid

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Properties

Quality Segment

100

assay

97%

form

liquid

refractive index

n20/D 1.457 (lit.)

bp

105-107 °C (lit.)

density

1.392 g/mL at 25 °C (lit.)

functional group

bromo

SMILES string

BrCC1CC1

InChI

1S/C4H7Br/c5-3-4-1-2-4/h4H,1-3H2

InChI key

AEILLAXRDHDKDY-UHFFFAOYSA-N

Description

General description

The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.

Application

(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

pictograms

GHS02,GHS07

signalword

Warning

hcodes

H226,H302

pcodes

P210 - P233 - P240 - P241 - P242 - P301 + P312

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

105.8 °F

flash_point_c

41 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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