242616
2-Bromoiodobenzene
99%
Synonym(s):
1-Bromo-2-iodobenzene, 1-Iodo-2-bromobenzene, 2-Bromo-1-iodobenzene, 2-Bromophenyl iodide, 2-Iodo-1-bromobenzene, 2-Iodobromobenzene, o-Bromoiodobenzene, o-Bromophenyl iodide, o-Iodobromobenzene
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About This Item
Linear Formula:
BrC6H4I
CAS Number:
Molecular Weight:
282.90
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
209-508-9
MDL number:
Assay:
99%
Form:
liquid
Quality Level
assay
99%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.661 (lit.)
bp
120-121 °C/15 mmHg (lit.)
mp
9-10 °C (lit.)
density
2.203 g/mL at 25 °C (lit.)
functional group
bromo, iodo
SMILES string
Brc1ccccc1I
InChI
1S/C6H4BrI/c7-5-3-1-2-4-6(5)8/h1-4H
InChI key
OIRHKGBNGGSCGS-UHFFFAOYSA-N
General description
2-bromoiodobenzene is an electrophile used in Pd-catalyzed cross-coupling reactions with amino-functionalized organozinc reagents.
Application
2-Bromoiodobenzene was used in the synthesis of diarylamines.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Routes toward enantiopure 2-substituted indolines: an overview
Anas, et al.
Tetrahedron Asymmetry, 20, 2193-2199 (2009)
Synthesis of 2-substituted indolines using sequential Pd-catalyzed processes
Deboves, et al.
Journal of the Chemical Society. Perkin Transactions 1, 733-736 (2002)
María E Budén et al.
The Journal of organic chemistry, 74(12), 4490-4498 (2009-05-23)
The synthesis of a series of substituted 9H-carbazoles by the photostimulated S(RN)1 substitution reaction with diarylamines as starting substrate was performed. The diarylamines were obtained by two approaches, the Pd-catalyzed reactions (Buchwald-Hartwig) or Cu-catalyzed reactions of 2-haloanilines with aryl halides
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 242616-5G | 04061837595257 |
| 242616-25G | 04061825589510 |