Skip to Content
Merck
CN

244775

Triphenyltin hydride

Synonym(s):

Triphenylstannane, Triphenylstannyl hydride

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Linear Formula:
(C6H5)3SnH
CAS Number:
892-20-6
Molecular Weight:
351.03
NACRES:
NA.22
PubChem Substance ID:
24854702
UNSPSC Code:
12352002
EC Number:
212-967-8
MDL number:
MFCD00003004
Form:
solid

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

InChI key

NFHRNKANAAGQOH-UHFFFAOYSA-N

InChI

1S/3C6H5.Sn.H/c3*1-2-4-6-5-3-1;;/h3*1-5H;;

SMILES string

c1ccc(cc1)[SnH](c2ccccc2)c3ccccc3

form

solid

reaction suitability

reagent type: reductant

refractive index

n20/D 1.632 (lit.)

bp

163-165 °C/0.3 mmHg (lit.)

mp

28 °C (lit.)

density

1.374 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Application

Triphenyltin hydride can be used as a reducing agent in:
  • The reductive deselenenylation reaction in the presence of the catalytic amount of AIBN.
  • The free radical hydrostannylations of olefins.
  • The reduction of α, β-unsaturated ketones and esters.

It can also be used as a radical precursor in the free-radical reduction reactions in the presence of 9-borabicyclo[3.3.1]nonane (9-BBN) as an initiator.

pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
SHBK1414
SHBG0370V
SHBD1686V
00830EW
09010MA

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Fabiane G Antes et al.
Environmental science & technology, 45(24), 10524-10530 (2011-11-15)
Triphenyltin (TPhT) is a biocide used worldwide in agriculture, especially in rice crop farming. The distribution and dissipation of TPhT in rice fields, as well as uptake of TPhT and other phenyltin compounds (monophenyltin, MPhT, and diphenyltin, DPhT) is still
Ítalo Braga Castro et al.
Environmental toxicology and chemistry, 31(5), 947-954 (2012-03-14)
The imposex incidence was appraised in South American gastropods, considering the scenario before and after the global ban of tributyltin (TBT). A statistically significant reduction in imposex indexes was observed in Stramonita haemastoma collected in 2006 and 2010 from areas
Sartaj Tabassum et al.
Metallomics : integrated biometal science, 4(2), 205-217 (2011-12-21)
The novel organotin complex 1-{(2-hydroxyethyl)amino}-2-amino-1,2-dideoxy-D-glucose triphenyltin(iv) (GATPT) was synthesized by the reaction of N-glycoside ligand and triphenyltin(iv) chloride. GATPT was characterized by elemental analyses, polarimetry, IR, CD, UV and multinuclear ((1)H, (13)C, (119)Sn) 1D and 2D NMR. The interaction of
Free radical hydrostannylation of unactivated alkenes with chiral trialkylstannanes
Kavanagh Y, et al.
Organometallics, 30(16), 4387-4392 (2011)
Zhenghong Zuo et al.
Aquatic toxicology (Amsterdam, Netherlands), 122-123, 106-112 (2012-07-04)
Tributyltin (TBT) and triphenyltin (TPT) coexist in the aquatic environment. However, the effects of TBT, TPT and a mixture of the two on DNA damage in marine fish livers and the mechanism involved remain to be elucidated. In the present
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service