Key Documents

View All Documentation

245305

(1R)-(−)-Menthyl chloroformate

Name: (1<I>R</I>)-(−)-Menthyl chloroformate
Brand: ALDRICH

optical purity ee: 99% (GLC)

Synonym(s):

(−)-Menthyl chloroformate

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):

C₁₁H₁₉ClO₂

CAS Number:

14602-86-9

Molecular Weight:

218.72

MDL number:

MFCD00009694

Beilstein/REAXYS Number:

2414686

UNSPSC Code:

12352101

NACRES:

NA.22

PubChem Substance ID:

24854513

Form:

liquid

Technical Service

Need help? Our team of experienced scientists is here for you.

Let Us Assist

Properties

vapor pressure

0.01 psi ( 20 °C)

form

liquid

optical activity

[α]20/D −83°, c = 1 in chloroform

optical purity

ee: 99% (GLC)

refractive index

n20/D 1.458 (lit.)

bp

108-109 °C/11 mmHg (lit.)

density

1.02 g/mL at 25 °C (lit.)

functional group

chloro

storage temp.

2-8°C

SMILES string

CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(Cl)=O

InChI

1S/C11H19ClO2/c1-7(2)9-5-4-8(3)6-10(9)14-11(12)13/h7-10H,4-6H2,1-3H3/t8-,9+,10-/m1/s1

InChI key

KIUPCUCGVCGPPA-KXUCPTDWSA-N

Description

Application

1R)-(-)-Menthyl chloroformate may be used in the preparation of 1-O-menthoxycarbonyl myo-inositol.

Chiral derivatizing agent used for the resolution of alcohols and amines by GC, HPLC, or crystallization.

Readily forms a chloroimidodicarbonate which asymmetrically chlorinates silyl enol ethers under mild conditions and in good yields.

pictograms

GHS06,GHS05

signalword

Danger

hcodes

H314,H331

pcodes

P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Inhalation - Skin Corr. 1B

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

158.0 °F - closed cup

flash_point_c

70 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library