246352
Methyl carbamate
98%
Synonym(s):
Urethylane
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About This Item
Linear Formula:
NH2COOCH3
CAS Number:
Molecular Weight:
75.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
209-939-2
MDL number:
Product Name
Methyl carbamate, 98%
InChI key
GTCAXTIRRLKXRU-UHFFFAOYSA-N
InChI
1S/C2H5NO2/c1-5-2(3)4/h1H3,(H2,3,4)
SMILES string
COC(N)=O
assay
98%
form
crystals
bp
176-177 °C (lit.)
mp
56-58 °C (lit.)
solubility
alcohol: freely soluble(lit.)
water: freely soluble(lit.)
functional group
amine
Quality Level
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Related Categories
Application
Methyl carbamate was used in the synthesis of protected aminocyclopropanes.
signalword
Warning
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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Shingo Ishikawa et al.
Angewandte Chemie (International ed. in English), 52(38), 10060-10063 (2013-08-06)
Easy as 1,2,3: Reaction of methyl carbamate, triethyl orthoformate, and readily available alkenes provides a highly practical preparation of protected aminocyclopropanes. The reaction proceeds with preferential cis addition to alkenes, and cleavage of the methyl carbamate gives the free aminocyclopropanes
N P Sen et al.
Food additives and contaminants, 9(2), 149-160 (1992-03-01)
A method is described for the simultaneous determination of methyl carbamate (MC) and ethyl carbamate (EC) in wines that is based on: (a) extraction of the sample with dichloromethane using an extraction tube or an alumina-Celite column, (b) concentration of
P C Chan et al.
Japanese journal of cancer research : Gann, 83(3), 258-263 (1992-03-01)
Short-term and long-term carcinogenicity of methyl carbamate (MCB) was evaluated in F344 rats and B6C3F1 mice. In experiments lasting 6, 12, and 18 months, MCB was given in water by gavage to groups of 10 male and 10 female rats
John E Casida et al.
Chemico-biological interactions, 203(1), 221-225 (2012-08-29)
The anticholinesterase (antiChE) organophosphorus (OP) and methylcarbamate (MC) insecticides have been used very effectively as contact and systemic plant protectants for seven decades. About 90 of these compounds are still in use - the largest number for any insecticide chemotype
Xusheng Shao et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(43), 17273-17277 (2013-10-11)
The nicotinic acetylcholine (ACh) receptor (nAChR) is the principal insecticide target. Nearly half of the insecticides by number and world market value are neonicotinoids acting as nAChR agonists or organophosphorus (OP) and methylcarbamate (MC) acetylcholinesterase (AChE) inhibitors. There was no
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