246921
1,8-Bis(bromomethyl)naphthalene
98%
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About This Item
Linear Formula:
C10H6(CH2Br)2
CAS Number:
Molecular Weight:
314.02
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
Product Name
1,8-Bis(bromomethyl)naphthalene, 98%
InChI
1S/C12H10Br2/c13-7-10-5-1-3-9-4-2-6-11(8-14)12(9)10/h1-6H,7-8H2
SMILES string
BrCc1cccc2cccc(CBr)c12
InChI key
GCZOMCDXYFMAGP-UHFFFAOYSA-N
assay
98%
form
crystals
mp
131-133 °C (lit.)
functional group
bromo
Application
1,8-Bis(bromomethyl)naphthalene has been used in the synthesis of indan-based unusual α-amino acid derivatives under solid-liquid phase-transfer catalysis conditions.
General description
Two-photon chemistry of 1,8-bis(bromomethyl)naphthalene has been studied by time-delayed, two-color photolysis and argon ion laser-jet photolysis techniques.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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Two-Photon Laser-Induced Reaction of 1, 8-Bis (halomethyl) naphthalenes from Different Excited States and Transient Targeting of Its Intermediate by Time-Delayed, Two-Color Photolysis and Argon Ion Laser-Jet Photolysis Techniques
Ouchi A, et al.
Journal of the American Chemical Society, 119(3), 592-599 (1997)
S Kotha et al.
The Journal of organic chemistry, 65(5), 1359-1365 (2000-05-18)
Conformationally constrained cyclic alpha-amino acid derivatives were synthesized under solid-liquid phase-transfer catalysis conditions. This methodology involves the bis-alkylation of ethyl isocyanoacetate with various alpha,alpha'-dibromo-o-xylene derivatives [alpha,alpha'-dibromo-o-xylene 5, 2,3-bis(bromomethyl)-1, 4-dimethoxybenzene 6, 1,2-bis(bromomethyl)-4,5-dibromobenzene 7, 2, 3-bis(bromomethyl)naphthalene 8, 1,8-bis(bromomethyl)-naphthalene 9, 6,7-bis(bromomethyl)-2,2-dimethyl-1H-phenalene-1,3(2H)-dione 10, 2
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