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Merck
CN

246921

1,8-Bis(bromomethyl)naphthalene

98%

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About This Item

Linear Formula:
C10H6(CH2Br)2
CAS Number:
Molecular Weight:
314.02
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
Assay:
98%
Form:
crystals
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assay

98%

form

crystals

mp

131-133 °C (lit.)

functional group

bromo

SMILES string

BrCc1cccc2cccc(CBr)c12

InChI

1S/C12H10Br2/c13-7-10-5-1-3-9-4-2-6-11(8-14)12(9)10/h1-6H,7-8H2

InChI key

GCZOMCDXYFMAGP-UHFFFAOYSA-N

General description

Two-photon chemistry of 1,8-bis(bromomethyl)naphthalene has been studied by time-delayed, two-color photolysis and argon ion laser-jet photolysis techniques.

Application

1,8-Bis(bromomethyl)naphthalene has been used in the synthesis of indan-based unusual α-amino acid derivatives under solid-liquid phase-transfer catalysis conditions.


pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Two-Photon Laser-Induced Reaction of 1, 8-Bis (halomethyl) naphthalenes from Different Excited States and Transient Targeting of Its Intermediate by Time-Delayed, Two-Color Photolysis and Argon Ion Laser-Jet Photolysis Techniques
Ouchi A, et al.
Journal of the American Chemical Society, 119(3), 592-599 (1997)
S Kotha et al.
The Journal of organic chemistry, 65(5), 1359-1365 (2000-05-18)
Conformationally constrained cyclic alpha-amino acid derivatives were synthesized under solid-liquid phase-transfer catalysis conditions. This methodology involves the bis-alkylation of ethyl isocyanoacetate with various alpha,alpha'-dibromo-o-xylene derivatives [alpha,alpha'-dibromo-o-xylene 5, 2,3-bis(bromomethyl)-1, 4-dimethoxybenzene 6, 1,2-bis(bromomethyl)-4,5-dibromobenzene 7, 2, 3-bis(bromomethyl)naphthalene 8, 1,8-bis(bromomethyl)-naphthalene 9, 6,7-bis(bromomethyl)-2,2-dimethyl-1H-phenalene-1,3(2H)-dione 10, 2



Global Trade Item Number

SKUGTIN
246921-250MG04061833482087