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Merck
CN

247057

Tetrabutylammonium (meta)periodate

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About This Item

Linear Formula:
(CH3CH2CH2CH2)4N(IO4)
CAS Number:
65201-77-6
Molecular Weight:
433.37
UNSPSC Code:
12352302
NACRES:
NA.23
PubChem Substance ID:
24854846
EC Number:
265-614-5
Beilstein/REAXYS Number:
4621593
MDL number:
MFCD00011852
Form:
solid

Key Documents

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InChI key

PYVXLMQALOZKES-UHFFFAOYSA-M

InChI

1S/C16H36N.HIO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1

SMILES string

[O-]I(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC

form

solid

reaction suitability

reagent type: oxidant

concentration

29.3% iodine (titration)

mp

175 °C (dec.) (lit.)

Quality Level

100

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Application

Tetrabutylammonium (meta)periodate (DCM) can be oxidated for the synthesis of aryl nitroso derivatives. It can also be used in the formation of an ionic liquid for the synthesis of aromatic carboxylic acids.

pictograms

Flame over circleExclamation mark
GHS03,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCBT2287
BCBQ1374V
BCBM0658V
STBC8940V
STBC8939V

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Efficient synthesis of aromatic carboxylic acids from aryl ketones in ionic liquid
Lee JC and Lee J
Synthetic Communications, 36(8), 1071-1074 (2006)
Study of Enantioselective Catalysis of Nitroso-Diels-Alder Reaction on Solid Support
Kratka L and Hlavavc J
ChemistrySelect, 2(14), 3987-3992 (2017)
Carmen E Castillo et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(15), 4946-4954 (2020-12-23)
Oxoiron(IV) complexes bearing tetradentate ligands have been extensively studied as models for the active oxidants in non-heme iron-dependent enzymes. These species are commonly generated by oxidation of their ferrous precursors. The mechanisms of these reactions have seldom been investigated. In
Michelle L Ingalsbe et al.
Bioorganic & medicinal chemistry letters, 19(17), 4984-4987 (2009-08-08)
Due to the increasing number of strains of drug-resistant bacteria, the development of new antibiotics has become increasingly important. The antibacterial properties of quaternary amines and their derivatives on both Gram-positive and Gram-negative bacteria are well known. However, an encompassing

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