247219
6-Bromo-1-hexene
95%
Synonym(s):
1-Bromo-5-hexene, 5-Hexen-1-yl bromide, 5-Hexenyl bromide, 6-Bromohexene
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About This Item
Linear Formula:
Br(CH2)4CH=CH2
CAS Number:
Molecular Weight:
163.06
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
506203
Assay:
95%
Form:
liquid
Quality Level
assay
95%
form
liquid
impurities
<3% DMF
refractive index
n20/D 1.465 (lit.)
bp
47-51 °C/16 mmHg (lit.)
density
1.22 g/mL at 25 °C (lit.)
functional group
alkyl halide, allyl, bromo
SMILES string
BrCCCCC=C
InChI
1S/C6H11Br/c1-2-3-4-5-6-7/h2H,1,3-6H2
InChI key
RIMXEJYJXDBLIE-UHFFFAOYSA-N
General description
Reaction of 6-bromo-1-hexene with Mg to form Grignard compounds has been investigated. The thermal chemistry of 6-bromo-1-hexene on Ni (100) surface has been studied under ultrahigh vacuum conditions by X-ray photoelectron spectroscopy and temperature-programmed desorption.
Application
6-Bromo-1-hexene was used in the preparation of epoxide, 6-bromo-1,2-epoxyhexane. It was also used in a simple, direct preparation of 4-alkenylbenzonitriles via anionic reduced forms of terephthalonitrile in liquid ammonia.
signalword
Danger
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
129.2 °F - closed cup
flash_point_c
54 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Synlett, 1616-1616 (2007)
Cyclization of 6-bromo-1, 2-epoxyhexane promoted by metal-halogen exchange: unexpected regioselectivity.
Babler JH and Bauta WE.
Tetrahedron Letters, 25(39), 4323-4324 (1984)
Thermal chemistry of 1, 6-diiodohexane on Ni (100) single-crystal surfaces: Mimicking cyclization reactions.
Tjandra S and Zaera F.
The Journal of Physical Chemistry A, 103(!4), 2312-2320 (1999)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 247219-5G | 04061825883946 |
| 247219-1G | 04061837071836 |