249580
9-Fluorenone-4-carbonyl chloride
97%
Synonym(s):
9-Oxo-4-fluorenecarbonyl chloride
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About This Item
Empirical Formula (Hill Notation):
C14H7ClO2
CAS Number:
Molecular Weight:
242.66
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
solid
InChI
1S/C14H7ClO2/c15-14(17)11-7-3-6-10-12(11)8-4-1-2-5-9(8)13(10)16/h1-7H
SMILES string
ClC(=O)c1cccc2C(=O)c3ccccc3-c12
InChI key
XKCGWCQMEUASJF-UHFFFAOYSA-N
assay
97%
form
solid
impurities
<2% dichloromethane
mp
139-141 °C (lit.)
storage temp.
2-8°C
General description
9-Fluorenone-4-carbonyl chloride is a fluorescent electrophilic reagent.
Application
9-Fluorenone-4-carbonyl chloride was used to functionalize amino acids in alkaline medium before their enantioresolution by HPLC. It was also used in the synthesis of N-(2-hydroxyethyl)-9-oxo-9H-fluorene-4 carboxamide.
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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9-Fluorenon-4-carboxamides: synthesis, conformational analysis, anti-HSV-2, and immunomodulatory evaluation. Note II.
Alcaro S, et al.
ARKIVOC (Gainesville, FL, United States), 334, 348-348 (2004)
T-J Hsien et al.
Amino acids, 33(1), 97-104 (2006-10-28)
A fluorescent electrophilic reagent, 9-fluorenone-4-carbonyl chloride (FCC), is chosen to functionalize amino acids in alkaline medium before their HPLC resolution. FCC reacts with both primary and secondary amino acids to produce stable and highly fluorescent derivatives suitable for sensitive and
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