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Merck
CN

249939

Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer

96%, powder

Synonym(s):

[Rh(nbd)Cl]2, dichlorobis(norbornadiene)dirhodium, 2,5-Norbornadiene-rhodium(I) chloride dimer, Chloro(2,5-norbornadiene)rhodium(I) dimer, Rhodium(I) chloride 2,5-Norbornadiene complex dimer, [Rh(nbd)Cl]2

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About This Item

Empirical Formula (Hill Notation):
C14H16Cl2Rh2
CAS Number:
Molecular Weight:
460.99
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
235-510-4
MDL number:
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Product Name

Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer, 96%

InChI key

RXDWVIOULPVOEO-SEGRDSFWSA-L

InChI

1S/2C7H8.2ClH.2Rh/c2*1-2-7-4-3-6(1)5-7;;;;/h2*1-4,6-7H,5H2;2*1H;;/q;;;;2*+1/p-2/t2*6-,7+;;;;

SMILES string

Cl[Rh].Cl[Rh].[CH]1[CH]C2[CH][CH]C1C2.[CH]3[CH]C4[CH][CH]C3C4

assay

96%

form

powder

reaction suitability

core: rhodium, reagent type: catalyst

Quality Level

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.

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