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Merck
CN

251232

Tetraisopropylthiuram disulfide

98%

Synonym(s):

Bis(diisopropylthiocarbamoyl) disulfide

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About This Item

Linear Formula:
([(CH3)2CH]2NC((S)S]2
CAS Number:
Molecular Weight:
352.65
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
98%
Form:
powder
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InChI

1S/C14H28N2S4/c1-9(2)15(10(3)4)13(17)19-20-14(18)16(11(5)6)12(7)8/h9-12H,1-8H3

SMILES string

CC(C)N(C(C)C)C(=S)SSC(=S)N(C(C)C)C(C)C

InChI key

ZUYREEAWHZRZDX-UHFFFAOYSA-N

assay

98%

form

powder

mp

115-117 °C (lit.)

solubility

chloroform: soluble 2.5%, clear, yellow

functional group

amine, disulfide

Application

Tetraisopropylthiuram disulphide has been used:
  • for incorporation of a thiol equivalent into heterocyclic compounds, by reaction with appropriate lithiated heterocycle
  • in preparation of unsymmetrical sulfides
  • as extractant for silver (I) extraction from photographic fixing solution

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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New synthesis of unsymmetrical dithia compounds.
Smith K and Tzimas M.
Journal of the Chemical Society. Perkin Transactions 1, 19, 2381-2382 (1995)
Silver extraction for pollution control of photographic fixing solution with tetramethylthiuram disulfide.
Mendoza CS and Kamata S.
Bulletin of the Chemical Society of Japan, 69(12), 3499-3504 (1996)

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