Skip to Content
Merck
CN

251496

(−)-Isopinocampheylborane TMEDA complex

Synonym(s):

(−)-N,N′-Bis(monoisopinocampheylborane)-N,N,N′,N′-tetramethylethylenediamine, (R)-Alpine-Boramine

Sign In to View Organizational & Contract Pricing.

Select a Size


About This Item

Empirical Formula (Hill Notation):
C13H27BN
CAS Number:
Molecular Weight:
208.17
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

InChI

1S/2C10H19B.C6H16N2/c2*1-6-8-4-7(5-9(6)11)10(8,2)3;1-7(2)5-6-8(3)4/h2*6-9H,4-5,11H2,1-3H3;5-6H2,1-4H3/t2*6-,7+,8-,9-;/m00./s1

SMILES string

CN(C)CCN(C)C.[H][C@]12C[C@H](B)[C@@H](C)[C@]([H])(C1)C2(C)C.[H][C@]34C[C@H](B)[C@@H](C)[C@]([H])(C3)C4(C)C

InChI key

QNDCJVKDHWRHGS-NCHGFZPDSA-N

form

solid

functional group

amine

Application

Chiral hydroboration reagent.This amine-borane complex has been used as a polarity-reversal catalyst for the kinetic resolution of racemic esters and ketones.

Legal Information

Alpine-Boramine is a trademark of Sigma-Aldrich Co. LLC

pictograms

FlameExclamation mark

signalword

Warning

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Water-react. 3

Regulatory Information

新产品
This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

The Journal of Organic Chemistry, 45, 3543-3543 (1980)
Dang, H.-S. et al.
Journal of the Chemical Society. Perkin Transactions 1, 1033-1033 (1994)
Aldrichimica Acta, 20, 30-30 (1987)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service