254584
Crotyl chloride, predominantly trans
95%
Synonym(s):
1-Chloro-2-butene
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Linear Formula:
CH3CH=CHCH2Cl
CAS Number:
Molecular Weight:
90.55
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
225-516-5
MDL number:
Assay:
95%
Form:
liquid
InChI key
YTKRILODNOEEPX-NSCUHMNNSA-N
InChI
1S/C4H7Cl/c1-2-3-4-5/h2-3H,4H2,1H3/b3-2+
SMILES string
[H]\C(C)=C(\[H])CCl
assay
95%
form
liquid
impurities
4% 3-chloro-1-butene
refractive index
n20/D 1.436 (lit.)
bp
84-85 °C (lit.)
density
0.929 g/mL at 25 °C (lit.)
functional group
alkyl halide, chloro
storage temp.
2-8°C
Quality Level
Related Categories
General description
Crotyl chloride reacts with trichlorosilane in the presence of tertiary amine and copper salt to give the corresponding allyltrichlorosilane.
Application
Crotyl chloride was used in kinetics measurements of reactions of atomic chlorine with series of unsaturated aldehydes and ketones at 298K. (E)Crotyl chloride was also used in the preparation of (E)-crotyltrichlorosilane.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
23.0 °F
flash_point_c
-5 °C
Regulatory Information
危险化学品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Stereohomogeneous synthesis of (E)-and (Z)-crotyltrifluorosilanes and highly stereoselective allylation of aldehydes.
Kira M, et al.
Tetrahedron Letters, 30(9), 1099-1102 (1989)
The condensation reaction of trichlorosilane with allylic chlorides catalyzed by copper salts in the presence of a tertiary amine.
Furuya N and Sukawa T.
Journal of Organometallic Chemistry, 96(1), C1-C3 (1975)
Rate constants for the reactions of chlorine atoms with a series of unsaturated aldehydes and ketones at 298 K: structure and reactivity.
Wang W, et al.
Physical Chemistry Chemical Physics, 4(10), 1824-1831 (2002)
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service