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255831

Germanium(IV) chloride

99.999% trace metals basis

Synonym(s):

Germanium tetrachloride

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About This Item

Linear Formula:
GeCl4
CAS Number:
10038-98-9
Molecular Weight:
214.45
NACRES:
NA.23
PubChem Substance ID:
24855486
UNSPSC Code:
12352302
EC Number:
233-116-7
MDL number:
MFCD00011029
Assay:
99.999% trace metals basis
Form:
liquid
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vapor pressure

76 mmHg ( 20 °C)

assay

99.999% trace metals basis

form

liquid

reaction suitability

reagent type: catalyst
core: germanium

impurities

≤15.0 ppm Trace Metal Analysis

bp

83 °C (lit.)

mp

−49.5 °C (lit.)

density

1.88 g/mL at 25 °C

SMILES string

Cl[Ge](Cl)(Cl)Cl

InChI

1S/Cl4Ge/c1-5(2,3)4

InChI key

IEXRMSFAVATTJX-UHFFFAOYSA-N

Application

Used in the microwave preparation of Ge2Cl6, a colorless crystalline material which was included in a further study of low-valent germanium compounds.

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Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH014

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Does not sustain combustion.

flash_point_c

Does not sustain combustion.

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
0000080999
0000076873
0000012284
MKBP2724V
MKBN2273V

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Ian R. Beattie et al.
Inorganic chemistry, 37(23), 6032-6034 (2001-10-24)
The Raman spectrum of Ge(2)Cl(6) shows close analogies with that of the isoelectronic [Ga(2)Cl(6)](2)(-). A band at 262 cm(-)(1) is assigned as principally a Ge-Ge stretching mode. The compound is very moisture-sensitive and decomposes readily in vacuo to give GeCl(4)
Murat Kaya et al.
Talanta, 84(1), 122-126 (2011-02-15)
A new chloride generation system was designed for the direct, sensitive, rapid and accurate determination of the total germanium in complex matrices. It was aimed to improve the detection limit of chloride generation technique by increasing the vapor pressure of
Zehui Zhang et al.
ChemSusChem, 4(1), 131-138 (2011-01-13)
Direct conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) catalyzed by germanium(IV) chloride in ionic liquids has been investigated in search of an efficient and environmentally friendly process. Monosaccharides D-fructose and D-glucose, disaccharides sucrose and maltose, and even the polysaccharide cellulose were
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Global Trade Item Number

SKUGTIN
255831-1G04061838084125
255831-10G04061838069627